A note on the transition state of radical addition reactions

D. T. Clark; I. W. Scanlan; J. C. Walton

doi:10.1016/0009-2614(78)85144-6

A note on the transition state of radical addition reactions

D. T. Clark^*, I. W. Scanlan, J. C. Walton

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

An ab initio MO study of the reaction of F¹ atoms and CH^- ₃ radicals with ethylene indicates that the transition state occurs later in the F¹ atom reaction and that there is considerable charge polarization in the alkene arising mainly from transfer of a β electron to fluorine.

Original language	English
Pages (from-to)	102-106
Number of pages	5
Journal	Chemical Physics Letters
Volume	55
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(78)85144-6
Publication status	Published - 1 Apr 1978

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title = "A note on the transition state of radical addition reactions",

abstract = "An ab initio MO study of the reaction of F1 atoms and CH- 3 radicals with ethylene indicates that the transition state occurs later in the F1 atom reaction and that there is considerable charge polarization in the alkene arising mainly from transfer of a β electron to fluorine.",

author = "Clark, {D. T.} and Scanlan, {I. W.} and Walton, {J. C.}",

year = "1978",

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doi = "10.1016/0009-2614(78)85144-6",

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AU - Clark, D. T.

AU - Scanlan, I. W.

AU - Walton, J. C.

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Y1 - 1978/4/1

N2 - An ab initio MO study of the reaction of F1 atoms and CH- 3 radicals with ethylene indicates that the transition state occurs later in the F1 atom reaction and that there is considerable charge polarization in the alkene arising mainly from transfer of a β electron to fluorine.

AB - An ab initio MO study of the reaction of F1 atoms and CH- 3 radicals with ethylene indicates that the transition state occurs later in the F1 atom reaction and that there is considerable charge polarization in the alkene arising mainly from transfer of a β electron to fluorine.

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DO - 10.1016/0009-2614(78)85144-6

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VL - 55

SP - 102

EP - 106

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1

ER -

A note on the transition state of radical addition reactions

Abstract

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