A new zinc pyromellitate, [(C4N2H12)0.5(NH2(CH3)2][Zn(C10H2O8)]·1.78H2O, with a layered structure

SV Ganesan; Philip Lightfoot; Srinivasan Natarajan

doi:10.1016/j.solidstatesciences.2004.03.032

A new zinc pyromellitate, [(C₄N₂H₁₂)_0.5(NH₂(CH₃)₂][Zn(C₁₀H₂O₈)]·1.78H₂O, with a layered structure

SV Ganesan, Philip Lightfoot, Srinivasan Natarajan

Research output: Contribution to journal › Article › peer-review

Abstract

A hydrothermal reaction of ZnO, HCl, pyromellitic acid, piperazine and water/DMF mixture gave rise to a layered Zn coordination polymer. The structure, determined by single crystal XRD, consists of a network of ZnO4 centers, tetrahedrally coordinated by pyromellitate anions giving rise to a two-dimensional sheet structure. The connectivity resembles a 4-connected network in which each Zn atom is connected to four BTEC anions and each BTEC anion is linked to four Zn2+ ions. The DMF, under hydrothermal conditions, has transformed into dimethylamine. Both the acid and polymer shows photoluminescence with the main emission band for the polymer at about 390 nm (lambda(ex) = 338 nm). Our continuing investigations clearly reveal that it is profitable to explore amine templated metal-organic frameworks. (C) 2004 Elsevier SAS. All rights reserved.

Original language	English
Pages (from-to)	757-762
Number of pages	6
Journal	Solid State Sciences
Volume	6
DOIs	https://doi.org/10.1016/j.solidstatesciences.2004.03.032
Publication status	Published - Jul 2004

Keywords

zinc
hydrothermal
pyromellitate
two-dimensional
BTC(2-)=1,2,4,5-BENZENETETRACARBOXYLIC ACID DIANION
HEXAAZA MACROCYCLIC COMPLEXES
COORDINATION POLYMERS
CRYSTAL-STRUCTURE
HYDROTHERMAL SYNTHESIS
1,2,4,5-BENZENETETRACARBOXYLIC ACID
MAGNETIC-PROPERTIES
COPPER(II)
FRAMEWORK
CLUSTERS

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@article{8452e4913bca44109e09397ce150af99,

title = "A new zinc pyromellitate, [(C4N2H12)0.5(NH2(CH3)2][Zn(C10H2O8)]·1.78H2O, with a layered structure",

abstract = "A hydrothermal reaction of ZnO, HCl, pyromellitic acid, piperazine and water/DMF mixture gave rise to a layered Zn coordination polymer. The structure, determined by single crystal XRD, consists of a network of ZnO4 centers, tetrahedrally coordinated by pyromellitate anions giving rise to a two-dimensional sheet structure. The connectivity resembles a 4-connected network in which each Zn atom is connected to four BTEC anions and each BTEC anion is linked to four Zn2+ ions. The DMF, under hydrothermal conditions, has transformed into dimethylamine. Both the acid and polymer shows photoluminescence with the main emission band for the polymer at about 390 nm (lambda(ex) = 338 nm). Our continuing investigations clearly reveal that it is profitable to explore amine templated metal-organic frameworks. (C) 2004 Elsevier SAS. All rights reserved.",

keywords = "zinc, hydrothermal, pyromellitate, two-dimensional, BTC(2-)=1,2,4,5-BENZENETETRACARBOXYLIC ACID DIANION, HEXAAZA MACROCYCLIC COMPLEXES, COORDINATION POLYMERS, CRYSTAL-STRUCTURE, HYDROTHERMAL SYNTHESIS, 1,2,4,5-BENZENETETRACARBOXYLIC ACID, MAGNETIC-PROPERTIES, COPPER(II), FRAMEWORK, CLUSTERS",

author = "SV Ganesan and Philip Lightfoot and Srinivasan Natarajan",

year = "2004",

month = jul,

doi = "10.1016/j.solidstatesciences.2004.03.032",

language = "English",

volume = "6",

pages = "757--762",

journal = "Solid State Sciences",

issn = "1293-2558",

publisher = "Elsevier Masson s.r.l.",

}

TY - JOUR

T1 - A new zinc pyromellitate, [(C4N2H12)0.5(NH2(CH3)2][Zn(C10H2O8)]·1.78H2O, with a layered structure

AU - Ganesan, SV

AU - Lightfoot, Philip

AU - Natarajan, Srinivasan

PY - 2004/7

Y1 - 2004/7

N2 - A hydrothermal reaction of ZnO, HCl, pyromellitic acid, piperazine and water/DMF mixture gave rise to a layered Zn coordination polymer. The structure, determined by single crystal XRD, consists of a network of ZnO4 centers, tetrahedrally coordinated by pyromellitate anions giving rise to a two-dimensional sheet structure. The connectivity resembles a 4-connected network in which each Zn atom is connected to four BTEC anions and each BTEC anion is linked to four Zn2+ ions. The DMF, under hydrothermal conditions, has transformed into dimethylamine. Both the acid and polymer shows photoluminescence with the main emission band for the polymer at about 390 nm (lambda(ex) = 338 nm). Our continuing investigations clearly reveal that it is profitable to explore amine templated metal-organic frameworks. (C) 2004 Elsevier SAS. All rights reserved.

AB - A hydrothermal reaction of ZnO, HCl, pyromellitic acid, piperazine and water/DMF mixture gave rise to a layered Zn coordination polymer. The structure, determined by single crystal XRD, consists of a network of ZnO4 centers, tetrahedrally coordinated by pyromellitate anions giving rise to a two-dimensional sheet structure. The connectivity resembles a 4-connected network in which each Zn atom is connected to four BTEC anions and each BTEC anion is linked to four Zn2+ ions. The DMF, under hydrothermal conditions, has transformed into dimethylamine. Both the acid and polymer shows photoluminescence with the main emission band for the polymer at about 390 nm (lambda(ex) = 338 nm). Our continuing investigations clearly reveal that it is profitable to explore amine templated metal-organic frameworks. (C) 2004 Elsevier SAS. All rights reserved.

KW - zinc

KW - hydrothermal

KW - pyromellitate

KW - two-dimensional

KW - BTC(2-)=1,2,4,5-BENZENETETRACARBOXYLIC ACID DIANION

KW - HEXAAZA MACROCYCLIC COMPLEXES

KW - COORDINATION POLYMERS

KW - CRYSTAL-STRUCTURE

KW - HYDROTHERMAL SYNTHESIS

KW - 1,2,4,5-BENZENETETRACARBOXYLIC ACID

KW - MAGNETIC-PROPERTIES

KW - COPPER(II)

KW - FRAMEWORK

KW - CLUSTERS

UR - https://www.scopus.com/pages/publications/3242712381

UR - http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6W6W-4CG0N9T-5&_user=1026342&_coverDate=05%2F25%2F2004&_alid=178566517&_rdoc=2&_fmt=full&_orig=search&_cdi=6609&_sort=d&_st=4&_docanchor=&_acct=C000050565&_version=1&_urlVersion=0&_userid=1026342&md5=0a237e26eda947e8b3a8a2bdefd59bcb

U2 - 10.1016/j.solidstatesciences.2004.03.032

DO - 10.1016/j.solidstatesciences.2004.03.032

M3 - Article

SN - 1293-2558

VL - 6

SP - 757

EP - 762

JO - Solid State Sciences

JF - Solid State Sciences

ER -