TY - JOUR
T1 - A new methodology for zeolite analogue synthesis using ionic liquids as solvent and template
AU - Cooper, E R
AU - Andrews, C D
AU - Wheatley, Paul Stewart
AU - Webb, Paul Brian
AU - Wormald, Philip
AU - Morris, Russell Edward
PY - 2005
Y1 - 2005
N2 - Here we report a new method of preparing aluminophosphate zeolite analogues using ionic liquids [1] as both solvent and template [2]. An imidazolium-based ionic liquid leads to four zeotype frameworks under different conditions. One material has a novel structure type with unusual structural characteristics that can be traced back to the solvent chemistry. Because of the vanishingly low vapour pressure of ionic liquids this synthesis takes place at ambient pressure, eliminating any safety concerns associated with high hydrothermal pressures. The ionic liquid call also be recycled for further use.
AB - Here we report a new method of preparing aluminophosphate zeolite analogues using ionic liquids [1] as both solvent and template [2]. An imidazolium-based ionic liquid leads to four zeotype frameworks under different conditions. One material has a novel structure type with unusual structural characteristics that can be traced back to the solvent chemistry. Because of the vanishingly low vapour pressure of ionic liquids this synthesis takes place at ambient pressure, eliminating any safety concerns associated with high hydrothermal pressures. The ionic liquid call also be recycled for further use.
U2 - 10.1016/S0167-2991(05)80346-5
DO - 10.1016/S0167-2991(05)80346-5
M3 - Article
SN - 0167-2991
VL - 158
SP - 245
EP - 254
JO - Studies in Surface Science and Catalysis
JF - Studies in Surface Science and Catalysis
IS - A
ER -