A New Crystalline Zwitterionic Product from the Reaction of Bu3P and DMAD

Robert Alan Aitken; Stephen John Costello; Alexandra Martha Zoya Slawin; Neil James Wilson

doi:10.1002/ejoc.200390101

A New Crystalline Zwitterionic Product from the Reaction of Bu₃P and DMAD

Robert Alan Aitken, Stephen John Costello, Alexandra Martha Zoya Slawin, Neil James Wilson

Research output: Contribution to journal › Article › peer-review

Abstract

Tributylphosphane reacts with DMAD to give the crystalline adduct 2 which is stabilised by extensive delocalisation and whose formation involves an unusual rearrangement. The isomeric structure 7 for the previously reported adduct with triphenylphosphane is supported by C-13 NMR spectroscopy.

Original language	English
Pages (from-to)	623-625
Number of pages	3
Journal	European Journal of Organic Chemistry
Volume	2003
Issue number	4
DOIs	https://doi.org/10.1002/ejoc.200390101
Publication status	Published - Feb 2003

Keywords

rearrangements
zwitterions
phosphanes

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10.1002/ejoc.200390101

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title = "A New Crystalline Zwitterionic Product from the Reaction of Bu3P and DMAD",

abstract = "Tributylphosphane reacts with DMAD to give the crystalline adduct 2 which is stabilised by extensive delocalisation and whose formation involves an unusual rearrangement. The isomeric structure 7 for the previously reported adduct with triphenylphosphane is supported by C-13 NMR spectroscopy.",

keywords = "rearrangements, zwitterions, phosphanes",

author = "Aitken, {Robert Alan} and Costello, {Stephen John} and Slawin, {Alexandra Martha Zoya} and Wilson, {Neil James}",

year = "2003",

month = feb,

doi = "10.1002/ejoc.200390101",

language = "English",

volume = "2003",

pages = "623--625",

journal = "European Journal of Organic Chemistry",

issn = "1434-193X",

publisher = "Wiley-VCH, Weinheim",

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T1 - A New Crystalline Zwitterionic Product from the Reaction of Bu3P and DMAD

AU - Aitken, Robert Alan

AU - Costello, Stephen John

AU - Slawin, Alexandra Martha Zoya

AU - Wilson, Neil James

PY - 2003/2

Y1 - 2003/2

N2 - Tributylphosphane reacts with DMAD to give the crystalline adduct 2 which is stabilised by extensive delocalisation and whose formation involves an unusual rearrangement. The isomeric structure 7 for the previously reported adduct with triphenylphosphane is supported by C-13 NMR spectroscopy.

AB - Tributylphosphane reacts with DMAD to give the crystalline adduct 2 which is stabilised by extensive delocalisation and whose formation involves an unusual rearrangement. The isomeric structure 7 for the previously reported adduct with triphenylphosphane is supported by C-13 NMR spectroscopy.

KW - rearrangements

KW - zwitterions

KW - phosphanes

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UR - http://www3.interscience.wiley.com/cgi-bin/fulltext/102526766/PDFSTART

U2 - 10.1002/ejoc.200390101

DO - 10.1002/ejoc.200390101

M3 - Article

SN - 1434-193X

VL - 2003

SP - 623

EP - 625

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 4

ER -

A New Crystalline Zwitterionic Product from the Reaction of Bu₃P and DMAD

Abstract

Keywords

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