A new calcium trimellitate coordination polymer with a chain-like structure

Christophe Volkringer; Thierry Loiseau; Gerard Ferey; John E. Warren; David S. Wragg; Russell E. Morris

doi:10.1016/j.solidstatesciences.2007.04.002

A new calcium trimellitate coordination polymer with a chain-like structure

Christophe Volkringer
, Thierry Loiseau
, Gerard Ferey
, John E. Warren
, David S. Wragg
, Russell E. Morris

Research output: Contribution to journal › Article › peer-review

Abstract

The calcium trimellitate, Ca(H2O)[(O2C)(2)-C6H3-CO2H], was hydrothermally synthesized from a mixture of calcium hydroxide, 1,2,4-benzenetricarboxylic (or trimellitic) acid and water at 180 degrees C for 24 h (under autogenous pressure). Its crystal structure has been determined by single-crystal X-ray diffraction analysis using synchrotron radiation (station 9.8, SRS Daresbury, UK). It consists of infinite chains of calcium bicapped trigonal prismatic polyhedra connected to each other through the 1,2,4-benzenetricarboxylate ligand. The eight-fold coordinated calcium cation is bonded to one terminal water molecule, two carboxylate groups with a chelating conformation and three carboxylate groups in a monodentating mode. One of the monodentate carboxylate is terminal with the occurrence of protonated C-OH bonding. Triclinic space group P-1 with a = 6.9073(4) angstrom, b = 6.9917(4) angstrom, c = 10.3561(6) angstrom, alpha = 87.178(1)degrees, beta = 83.233(1)degrees, gamma = 69.576(1)degrees, V = 465.41(5) angstrom(3). (C) 2007 Elsevier Masson SAS. All rights reserved.

Original language	English
Pages (from-to)	455-458
Number of pages	4
Journal	Solid State Sciences
Volume	9
DOIs	https://doi.org/10.1016/j.solidstatesciences.2007.04.002
Publication status	Published - Jun 2007

Keywords

calcium
1,2,4-benzenetricarboxylate ligand
hydrothermal synthesis
crystal structure
METAL-ORGANIC FRAMEWORK
HYDROTHERMAL SYNTHESIS
LAYER STRUCTURE
DESIGN
ACID
COMPLEXES

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@article{f78834c7bd32458ea16668aa8fa208ef,

title = "A new calcium trimellitate coordination polymer with a chain-like structure",

abstract = "The calcium trimellitate, Ca(H2O)[(O2C)(2)-C6H3-CO2H], was hydrothermally synthesized from a mixture of calcium hydroxide, 1,2,4-benzenetricarboxylic (or trimellitic) acid and water at 180 degrees C for 24 h (under autogenous pressure). Its crystal structure has been determined by single-crystal X-ray diffraction analysis using synchrotron radiation (station 9.8, SRS Daresbury, UK). It consists of infinite chains of calcium bicapped trigonal prismatic polyhedra connected to each other through the 1,2,4-benzenetricarboxylate ligand. The eight-fold coordinated calcium cation is bonded to one terminal water molecule, two carboxylate groups with a chelating conformation and three carboxylate groups in a monodentating mode. One of the monodentate carboxylate is terminal with the occurrence of protonated C-OH bonding. Triclinic space group P-1 with a = 6.9073(4) angstrom, b = 6.9917(4) angstrom, c = 10.3561(6) angstrom, alpha = 87.178(1)degrees, beta = 83.233(1)degrees, gamma = 69.576(1)degrees, V = 465.41(5) angstrom(3). (C) 2007 Elsevier Masson SAS. All rights reserved.",

keywords = "calcium, 1,2,4-benzenetricarboxylate ligand, hydrothermal synthesis, crystal structure, METAL-ORGANIC FRAMEWORK, HYDROTHERMAL SYNTHESIS, LAYER STRUCTURE, DESIGN, ACID, COMPLEXES",

author = "Christophe Volkringer and Thierry Loiseau and Gerard Ferey and Warren, \{John E.\} and Wragg, \{David S.\} and Morris, \{Russell E.\}",

year = "2007",

month = jun,

doi = "10.1016/j.solidstatesciences.2007.04.002",

language = "English",

volume = "9",

pages = "455--458",

journal = "Solid State Sciences",

issn = "1293-2558",

publisher = "Elsevier Masson s.r.l.",

}

TY - JOUR

T1 - A new calcium trimellitate coordination polymer with a chain-like structure

AU - Volkringer, Christophe

AU - Loiseau, Thierry

AU - Ferey, Gerard

AU - Warren, John E.

AU - Wragg, David S.

AU - Morris, Russell E.

PY - 2007/6

Y1 - 2007/6

N2 - The calcium trimellitate, Ca(H2O)[(O2C)(2)-C6H3-CO2H], was hydrothermally synthesized from a mixture of calcium hydroxide, 1,2,4-benzenetricarboxylic (or trimellitic) acid and water at 180 degrees C for 24 h (under autogenous pressure). Its crystal structure has been determined by single-crystal X-ray diffraction analysis using synchrotron radiation (station 9.8, SRS Daresbury, UK). It consists of infinite chains of calcium bicapped trigonal prismatic polyhedra connected to each other through the 1,2,4-benzenetricarboxylate ligand. The eight-fold coordinated calcium cation is bonded to one terminal water molecule, two carboxylate groups with a chelating conformation and three carboxylate groups in a monodentating mode. One of the monodentate carboxylate is terminal with the occurrence of protonated C-OH bonding. Triclinic space group P-1 with a = 6.9073(4) angstrom, b = 6.9917(4) angstrom, c = 10.3561(6) angstrom, alpha = 87.178(1)degrees, beta = 83.233(1)degrees, gamma = 69.576(1)degrees, V = 465.41(5) angstrom(3). (C) 2007 Elsevier Masson SAS. All rights reserved.

AB - The calcium trimellitate, Ca(H2O)[(O2C)(2)-C6H3-CO2H], was hydrothermally synthesized from a mixture of calcium hydroxide, 1,2,4-benzenetricarboxylic (or trimellitic) acid and water at 180 degrees C for 24 h (under autogenous pressure). Its crystal structure has been determined by single-crystal X-ray diffraction analysis using synchrotron radiation (station 9.8, SRS Daresbury, UK). It consists of infinite chains of calcium bicapped trigonal prismatic polyhedra connected to each other through the 1,2,4-benzenetricarboxylate ligand. The eight-fold coordinated calcium cation is bonded to one terminal water molecule, two carboxylate groups with a chelating conformation and three carboxylate groups in a monodentating mode. One of the monodentate carboxylate is terminal with the occurrence of protonated C-OH bonding. Triclinic space group P-1 with a = 6.9073(4) angstrom, b = 6.9917(4) angstrom, c = 10.3561(6) angstrom, alpha = 87.178(1)degrees, beta = 83.233(1)degrees, gamma = 69.576(1)degrees, V = 465.41(5) angstrom(3). (C) 2007 Elsevier Masson SAS. All rights reserved.

KW - calcium

KW - 1,2,4-benzenetricarboxylate ligand

KW - hydrothermal synthesis

KW - crystal structure

KW - METAL-ORGANIC FRAMEWORK

KW - HYDROTHERMAL SYNTHESIS

KW - LAYER STRUCTURE

KW - DESIGN

KW - ACID

KW - COMPLEXES

UR - https://www.scopus.com/pages/publications/34347337649

U2 - 10.1016/j.solidstatesciences.2007.04.002

DO - 10.1016/j.solidstatesciences.2007.04.002

M3 - Article

SN - 1293-2558

VL - 9

SP - 455

EP - 458

JO - Solid State Sciences

JF - Solid State Sciences

ER -

A new calcium trimellitate coordination polymer with a chain-like structure

Abstract

Keywords

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