A new anion conductive bismuth-vanadium oxyfluoride

AV Akopjan; TV Serov; VA Dolgikh; EI Ardaschnikova; Philip Lightfoot

doi:10.1039/b201049f

A new anion conductive bismuth-vanadium oxyfluoride

AV Akopjan, TV Serov, VA Dolgikh, EI Ardaschnikova, Philip Lightfoot

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Abstract

A new anion conductive oxyfluoride Bi2VO5F0.7 has been obtained. Its crystal structure, related to the well-known Aurivillius phases, has been determined from powder X-ray and neutron diffraction data combined with a piezo test and magnetic measurements (I4mm, a = 3.869(3) Angstrom, c = 15.648(6) Angstrom, R-p = 4.41, R-wp = 9.50%). The transport properties of this compound have been studied as a function of temperature by impedance spectroscopy. The relation of the Bi2VO5F0.7 crystal structure and anion conductivity with different modifications of Bi2VO5.5 oxide is discussed.

Original language	English
Pages (from-to)	1490-1494
Number of pages	5
Journal	Journal of Materials Chemistry
Volume	12
DOIs	https://doi.org/10.1039/b201049f
Publication status	Published - 2002

Keywords

OXIDE-ION CONDUCTORS
AURIVILLIUS PHASES
BIMEVOX SERIES

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title = "A new anion conductive bismuth-vanadium oxyfluoride",

abstract = "A new anion conductive oxyfluoride Bi2VO5F0.7 has been obtained. Its crystal structure, related to the well-known Aurivillius phases, has been determined from powder X-ray and neutron diffraction data combined with a piezo test and magnetic measurements (I4mm, a = 3.869(3) Angstrom, c = 15.648(6) Angstrom, R-p = 4.41, R-wp = 9.50\%). The transport properties of this compound have been studied as a function of temperature by impedance spectroscopy. The relation of the Bi2VO5F0.7 crystal structure and anion conductivity with different modifications of Bi2VO5.5 oxide is discussed.",

keywords = "OXIDE-ION CONDUCTORS, AURIVILLIUS PHASES, BIMEVOX SERIES",

author = "AV Akopjan and TV Serov and VA Dolgikh and EI Ardaschnikova and Philip Lightfoot",

year = "2002",

doi = "10.1039/b201049f",

language = "English",

volume = "12",

pages = "1490--1494",

journal = "Journal of Materials Chemistry",

issn = "0959-9428",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - A new anion conductive bismuth-vanadium oxyfluoride

AU - Akopjan, AV

AU - Serov, TV

AU - Dolgikh, VA

AU - Ardaschnikova, EI

AU - Lightfoot, Philip

PY - 2002

Y1 - 2002

N2 - A new anion conductive oxyfluoride Bi2VO5F0.7 has been obtained. Its crystal structure, related to the well-known Aurivillius phases, has been determined from powder X-ray and neutron diffraction data combined with a piezo test and magnetic measurements (I4mm, a = 3.869(3) Angstrom, c = 15.648(6) Angstrom, R-p = 4.41, R-wp = 9.50%). The transport properties of this compound have been studied as a function of temperature by impedance spectroscopy. The relation of the Bi2VO5F0.7 crystal structure and anion conductivity with different modifications of Bi2VO5.5 oxide is discussed.

AB - A new anion conductive oxyfluoride Bi2VO5F0.7 has been obtained. Its crystal structure, related to the well-known Aurivillius phases, has been determined from powder X-ray and neutron diffraction data combined with a piezo test and magnetic measurements (I4mm, a = 3.869(3) Angstrom, c = 15.648(6) Angstrom, R-p = 4.41, R-wp = 9.50%). The transport properties of this compound have been studied as a function of temperature by impedance spectroscopy. The relation of the Bi2VO5F0.7 crystal structure and anion conductivity with different modifications of Bi2VO5.5 oxide is discussed.

KW - OXIDE-ION CONDUCTORS

KW - AURIVILLIUS PHASES

KW - BIMEVOX SERIES

UR - https://www.scopus.com/pages/publications/0036091124

U2 - 10.1039/b201049f

DO - 10.1039/b201049f

M3 - Article

SN - 0959-9428

VL - 12

SP - 1490

EP - 1494

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

ER -

A new anion conductive bismuth-vanadium oxyfluoride

Abstract

Keywords

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