A new 1-dimensional molybdenum phosphate: Synthesis and structure of [(CH3)4N][MN2MO6O12(OH)4(PO4)(HPO4)(H2PO4)2] · 4H2O

Philip Lightfoot; Diane Maason

doi:10.1016/0025-5408(95)00067-4

A new 1-dimensional molybdenum phosphate: Synthesis and structure of [(CH₃)₄N][MN₂MO₆O₁₂(OH)₄(PO₄)(HPO₄)(H₂PO₄)₂] · 4H₂O

Philip Lightfoot^*, Diane Maason

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A new 1-dimensional polymeric manganese molybdenophosphate, [(CH₃)₄N][Mn₂Mo₆O₁₂(OH)₄(PO₄)(HPO₄)(H₂PO₄)₂] · 4H₂O has been prepared hydrothermally. It crystallises in the triclinic system, P-1, with a = 12.583(4), b = 14.322(4), c = 12.365(5)Å, α = 104.70(3)°, β = 117.02(3)° and γ = 85.14(3)°. The structure is based on the [Mo₆O₁₂ (OH)₃(H_xPO₄)₄]^n- anion previously observed in several other molybdenophosphates. These units are linked together by two different manganese-containing layers into infinite anionic chains, which are linked together only by intervening TMA cations and H-bonds.

Original language	English
Pages (from-to)	1005-1013
Number of pages	9
Journal	Materials Research Bulletin
Volume	30
Issue number	8
DOIs	https://doi.org/10.1016/0025-5408(95)00067-4
Publication status	Published - 1 Jan 1995

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@article{15b745b247b4465ba368e1c4c4a8f799,

title = "A new 1-dimensional molybdenum phosphate: Synthesis and structure of [(CH3)4N][MN2MO6O12(OH)4(PO4)(HPO4)(H2PO4)2] · 4H2O",

abstract = "A new 1-dimensional polymeric manganese molybdenophosphate, [(CH3)4N][Mn2Mo6O12(OH)4(PO4)(HPO4)(H2PO4)2] · 4H2O has been prepared hydrothermally. It crystallises in the triclinic system, P-1, with a = 12.583(4), b = 14.322(4), c = 12.365(5){\AA}, α = 104.70(3)°, β = 117.02(3)° and γ = 85.14(3)°. The structure is based on the [Mo6O12 (OH)3(HxPO4)4]n- anion previously observed in several other molybdenophosphates. These units are linked together by two different manganese-containing layers into infinite anionic chains, which are linked together only by intervening TMA cations and H-bonds.",

author = "Philip Lightfoot and Diane Maason",

year = "1995",

month = jan,

day = "1",

doi = "10.1016/0025-5408(95)00067-4",

language = "English",

volume = "30",

pages = "1005--1013",

journal = "Materials Research Bulletin",

issn = "0025-5408",

publisher = "Elsevier",

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TY - JOUR

T1 - A new 1-dimensional molybdenum phosphate

T2 - Synthesis and structure of [(CH3)4N][MN2MO6O12(OH)4(PO4)(HPO4)(H2PO4)2] · 4H2O

AU - Lightfoot, Philip

AU - Maason, Diane

PY - 1995/1/1

Y1 - 1995/1/1

N2 - A new 1-dimensional polymeric manganese molybdenophosphate, [(CH3)4N][Mn2Mo6O12(OH)4(PO4)(HPO4)(H2PO4)2] · 4H2O has been prepared hydrothermally. It crystallises in the triclinic system, P-1, with a = 12.583(4), b = 14.322(4), c = 12.365(5)Å, α = 104.70(3)°, β = 117.02(3)° and γ = 85.14(3)°. The structure is based on the [Mo6O12 (OH)3(HxPO4)4]n- anion previously observed in several other molybdenophosphates. These units are linked together by two different manganese-containing layers into infinite anionic chains, which are linked together only by intervening TMA cations and H-bonds.

AB - A new 1-dimensional polymeric manganese molybdenophosphate, [(CH3)4N][Mn2Mo6O12(OH)4(PO4)(HPO4)(H2PO4)2] · 4H2O has been prepared hydrothermally. It crystallises in the triclinic system, P-1, with a = 12.583(4), b = 14.322(4), c = 12.365(5)Å, α = 104.70(3)°, β = 117.02(3)° and γ = 85.14(3)°. The structure is based on the [Mo6O12 (OH)3(HxPO4)4]n- anion previously observed in several other molybdenophosphates. These units are linked together by two different manganese-containing layers into infinite anionic chains, which are linked together only by intervening TMA cations and H-bonds.

UR - https://www.scopus.com/pages/publications/0029359291

U2 - 10.1016/0025-5408(95)00067-4

DO - 10.1016/0025-5408(95)00067-4

M3 - Article

AN - SCOPUS:0029359291

SN - 0025-5408

VL - 30

SP - 1005

EP - 1013

JO - Materials Research Bulletin

JF - Materials Research Bulletin

IS - 8

ER -

A new 1-dimensional molybdenum phosphate: Synthesis and structure of [(CH₃)₄N][MN₂MO₆O₁₂(OH)₄(PO₄)(HPO₄)(H₂PO₄)₂] · 4H₂O

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