A new 1-dimensional molybdenum phosphate: Synthesis and structure of [(CH3)4N][MN2MO6O12(OH)4(PO4)(HPO4)(H2PO4)2] · 4H2O

Philip Lightfoot*, Diane Maason

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

A new 1-dimensional polymeric manganese molybdenophosphate, [(CH3)4N][Mn2Mo6O12(OH)4(PO4)(HPO4)(H2PO4)2] · 4H2O has been prepared hydrothermally. It crystallises in the triclinic system, P-1, with a = 12.583(4), b = 14.322(4), c = 12.365(5)Å, α = 104.70(3)°, β = 117.02(3)° and γ = 85.14(3)°. The structure is based on the [Mo6O12 (OH)3(HxPO4)4]n- anion previously observed in several other molybdenophosphates. These units are linked together by two different manganese-containing layers into infinite anionic chains, which are linked together only by intervening TMA cations and H-bonds.

Original languageEnglish
Pages (from-to)1005-1013
Number of pages9
JournalMaterials Research Bulletin
Volume30
Issue number8
DOIs
Publication statusPublished - 1 Jan 1995

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