TY - JOUR
T1 - A new 1-dimensional molybdenum phosphate
T2 - Synthesis and structure of [(CH3)4N][MN2MO6O12(OH)4(PO4)(HPO4)(H2PO4)2] · 4H2O
AU - Lightfoot, Philip
AU - Maason, Diane
PY - 1995/1/1
Y1 - 1995/1/1
N2 - A new 1-dimensional polymeric manganese molybdenophosphate, [(CH3)4N][Mn2Mo6O12(OH)4(PO4)(HPO4)(H2PO4)2] · 4H2O has been prepared hydrothermally. It crystallises in the triclinic system, P-1, with a = 12.583(4), b = 14.322(4), c = 12.365(5)Å, α = 104.70(3)°, β = 117.02(3)° and γ = 85.14(3)°. The structure is based on the [Mo6O12 (OH)3(HxPO4)4]n- anion previously observed in several other molybdenophosphates. These units are linked together by two different manganese-containing layers into infinite anionic chains, which are linked together only by intervening TMA cations and H-bonds.
AB - A new 1-dimensional polymeric manganese molybdenophosphate, [(CH3)4N][Mn2Mo6O12(OH)4(PO4)(HPO4)(H2PO4)2] · 4H2O has been prepared hydrothermally. It crystallises in the triclinic system, P-1, with a = 12.583(4), b = 14.322(4), c = 12.365(5)Å, α = 104.70(3)°, β = 117.02(3)° and γ = 85.14(3)°. The structure is based on the [Mo6O12 (OH)3(HxPO4)4]n- anion previously observed in several other molybdenophosphates. These units are linked together by two different manganese-containing layers into infinite anionic chains, which are linked together only by intervening TMA cations and H-bonds.
UR - http://www.scopus.com/inward/record.url?scp=0029359291&partnerID=8YFLogxK
U2 - 10.1016/0025-5408(95)00067-4
DO - 10.1016/0025-5408(95)00067-4
M3 - Article
AN - SCOPUS:0029359291
SN - 0025-5408
VL - 30
SP - 1005
EP - 1013
JO - Materials Research Bulletin
JF - Materials Research Bulletin
IS - 8
ER -