A neutral heteroatomic zintl cluster for the catalytic hydrogenation of cyclic alkenes

Oliver P.E. Townrow; Cheuk Chung; Stuart A. Macgregor; Andrew S. Weller; Jose M. Goicoechea

doi:10.1021/jacs.0c09742

A neutral heteroatomic zintl cluster for the catalytic hydrogenation of cyclic alkenes

Oliver P.E. Townrow, Cheuk Chung, Stuart A. Macgregor, Andrew S. Weller^*, Jose M. Goicoechea^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

We report on the synthesis of an alkane-soluble Zintl cluster, [η4-Ge9(Hyp)3]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-clusterbased homogeneous catalyst.

Original language	English
Pages (from-to)	18330-18335
Number of pages	6
Journal	Journal of the American Chemical Society
Volume	142
Issue number	43
DOIs	https://doi.org/10.1021/jacs.0c09742
Publication status	Published - 28 Oct 2020

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abstract = "We report on the synthesis of an alkane-soluble Zintl cluster, [η4-Ge9(Hyp)3]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-clusterbased homogeneous catalyst.",

author = "Townrow, {Oliver P.E.} and Cheuk Chung and Macgregor, {Stuart A.} and Weller, {Andrew S.} and Goicoechea, {Jose M.}",

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AU - Chung, Cheuk

AU - Macgregor, Stuart A.

AU - Weller, Andrew S.

AU - Goicoechea, Jose M.

PY - 2020/10/28

Y1 - 2020/10/28

N2 - We report on the synthesis of an alkane-soluble Zintl cluster, [η4-Ge9(Hyp)3]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-clusterbased homogeneous catalyst.

AB - We report on the synthesis of an alkane-soluble Zintl cluster, [η4-Ge9(Hyp)3]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-clusterbased homogeneous catalyst.

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ER -

A neutral heteroatomic zintl cluster for the catalytic hydrogenation of cyclic alkenes

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