A luminescent [Pd4Ru8]24+ supramolecular cage

Diego Rota Martir; David B. Cordes; Alexandra M. Z. Slawin; Daniel Escudero; Denis Jacquemin; Stuart Warriner; Eli Zysman-Colman

doi:10.1039/C8CC02104J

A luminescent [Pd₄Ru₈]²⁴⁺ supramolecular cage

Diego Rota Martir, David B. Cordes, Alexandra M. Z. Slawin, Daniel Escudero, Denis Jacquemin, Stuart Warriner, Eli Zysman-Colman

Research output: Contribution to journal › Review article › peer-review

Abstract

A phosphorescent cage of the form [Pd₄Ru₈]²⁴⁺ is reported. The cage was formed using the metalloligand [Ru(dtbubpy)₂(qpy)]²⁺, where qpy = 4,4’:2’,2’’:4’’,4’’’-quaterpyridine and dtbubpy = 4,4’- ditert-butyl-2,2’-bipyridine. The cage has been characterised by NMR, ESI-MS, TEM and X-ray diffraction analyses and its emission properties elucidated by steady-state and time-resolved emission spectroscopy.

Original language	English
Pages (from-to)	6016-6019
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	47
Early online date	14 May 2018
DOIs	https://doi.org/10.1039/C8CC02104J
Publication status	Published - 14 Jun 2018

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10.1039/C8CC02104J

RuPd cage ver 14
© 2018 the Authors. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/C8CC02104J
Accepted author manuscript, 1.2 MB

Blue-Emitting Phospors: Blue-emitting Phosphors for Solid State Lighting Applications
Zysman-Colman, E. (PI)
EPSRC
1/06/15 → 30/09/19
Project: Standard

A Luminescent [Pd4Ru8] 24+ Supramolecular Cage (dataset)
Rota Martir, D. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator), Escudero, D. (Creator), Jacquemin, D. (Creator), Warriner, S. L. (Creator) & Zysman-Colman, E. (Creator), University of St Andrews, 31 May 2018
DOI: 10.17630/6c8bb687-b090-48dc-bed2-5087fa83f140
Dataset

File
CCDC 1828574 - 1828575: Experimental Crystal Structure Determination
Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator), Escudero, D. (Creator), Jacquemin, D. (Creator), Warriner, S. L. (Creator) & Zysman-Colman, E. (Creator), Cambridge Crystallographic Data Centre, 2018
https://dx.doi.org/10.5517/ccdc.csd.cc1zcs8d and one more link, https://dx.doi.org/10.5517/ccdc.csd.cc1zcs9f (show fewer)
Dataset

Cite this

@article{6d8ac5d5ae8f4d74a05187219f8b04c4,

title = "A luminescent [Pd4Ru8]24+ supramolecular cage",

abstract = "A phosphorescent cage of the form [Pd4Ru8]24+ is reported. The cage was formed using the metalloligand [Ru(dtbubpy)2(qpy)]2+, where qpy = 4,4{\textquoteright}:2{\textquoteright},2{\textquoteright}{\textquoteright}:4{\textquoteright}{\textquoteright},4{\textquoteright}{\textquoteright}{\textquoteright}-quaterpyridine and dtbubpy = 4,4{\textquoteright}- ditert-butyl-2,2{\textquoteright}-bipyridine. The cage has been characterised by NMR, ESI-MS, TEM and X-ray diffraction analyses and its emission properties elucidated by steady-state and time-resolved emission spectroscopy.",

author = "{Rota Martir}, Diego and Cordes, {David B.} and Slawin, {Alexandra M. Z.} and Daniel Escudero and Denis Jacquemin and Stuart Warriner and Eli Zysman-Colman",

note = "E.Z.-C. acknowledges the University of St Andrews and EPSRC (EP/M02105X/1) for financial support. D.E. thanks funding from the European Union{\textquoteright}s Horizon 2020 research and innovation programme under the Marie Sklodowska- Curie grant agreement No 700961. D.J. acknowledges the RFI Lumomat for financial support.",

year = "2018",

month = jun,

day = "14",

doi = "10.1039/C8CC02104J",

language = "English",

volume = "54",

pages = "6016--6019",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "47",

}

TY - JOUR

T1 - A luminescent [Pd4Ru8]24+ supramolecular cage

AU - Rota Martir, Diego

AU - Cordes, David B.

AU - Slawin, Alexandra M. Z.

AU - Escudero, Daniel

AU - Jacquemin, Denis

AU - Warriner, Stuart

AU - Zysman-Colman, Eli

N1 - E.Z.-C. acknowledges the University of St Andrews and EPSRC (EP/M02105X/1) for financial support. D.E. thanks funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska- Curie grant agreement No 700961. D.J. acknowledges the RFI Lumomat for financial support.

PY - 2018/6/14

Y1 - 2018/6/14

N2 - A phosphorescent cage of the form [Pd4Ru8]24+ is reported. The cage was formed using the metalloligand [Ru(dtbubpy)2(qpy)]2+, where qpy = 4,4’:2’,2’’:4’’,4’’’-quaterpyridine and dtbubpy = 4,4’- ditert-butyl-2,2’-bipyridine. The cage has been characterised by NMR, ESI-MS, TEM and X-ray diffraction analyses and its emission properties elucidated by steady-state and time-resolved emission spectroscopy.

AB - A phosphorescent cage of the form [Pd4Ru8]24+ is reported. The cage was formed using the metalloligand [Ru(dtbubpy)2(qpy)]2+, where qpy = 4,4’:2’,2’’:4’’,4’’’-quaterpyridine and dtbubpy = 4,4’- ditert-butyl-2,2’-bipyridine. The cage has been characterised by NMR, ESI-MS, TEM and X-ray diffraction analyses and its emission properties elucidated by steady-state and time-resolved emission spectroscopy.

U2 - 10.1039/C8CC02104J

DO - 10.1039/C8CC02104J

M3 - Review article

SN - 1359-7345

VL - 54

SP - 6016

EP - 6019

JO - Chemical Communications

JF - Chemical Communications

IS - 47

ER -

A luminescent [Pd4Ru8]24+ supramolecular cage

Abstract

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Projects

Blue-Emitting Phospors: Blue-emitting Phosphors for Solid State Lighting Applications

Datasets

A Luminescent [Pd4Ru8] 24+ Supramolecular Cage (dataset)

CCDC 1828574 - 1828575: Experimental Crystal Structure Determination

Cite this

A luminescent [Pd₄Ru₈]²⁴⁺ supramolecular cage