A luminescent 1D silver polymer containing [2.2]paracyclophane ligands

Campbell F. R. Mackenzie; Lucie Delforce; D. Rota Martir; David B. Cordes; Alexandra M. Z. Slawin; Eli Zysman-Colman

doi:10.3389/fchem.2021.728845

A luminescent 1D silver polymer containing [2.2]paracyclophane ligands

Campbell F. R. Mackenzie, Lucie Delforce, D. Rota Martir, David B. Cordes, Alexandra M. Z. Slawin, Eli Zysman-Colman^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

[2.2]Paracyclophane scaffolds have seen limited use as building blocks in supramolecular chemistry. Here, we report the synthesis and characterization of a 1D coordination polymer consisting of silver(I) ions bound to a [2.2]paracyclophane scaffold functionalized with two 4-pyridyl units. The structure of the polymer has been determined from single crystal X-ray diffraction analysis and reveals two different silver coordination motifs that alternate along the 1D coordination polymer. The coordination polymer exhibits strong blue and sky-blue fluorescence in solution and in the crystalline solid state, respectively.

Original language	English
Article number	728845
Number of pages	6
Journal	Frontiers in Chemistry
Volume	9
DOIs	https://doi.org/10.3389/fchem.2021.728845
Publication status	Published - 2 Aug 2021

Keywords

Coordination polymer
Cyclophane
Supramolecular chemistry
Silver

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10.3389/fchem.2021.728845Licence: CC BY

Mackenzie_2021_FC_1D_CC
Copyright © 2021 Mackenzie, Delforce, Rota Martir, Cordes, Slawin and Zysman-Colman. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
Final published version, 1.21 MBLicence: CC BY

Chemistry EPSRC-JSPS: EPSRC-JSPS Core-to-Core Grant Application
Zysman-Colman, E. (PI)
1/08/18 → 31/01/24
Project: Standard
Blue-Emitting Phospors: Blue-emitting Phosphors for Solid State Lighting Applications
Zysman-Colman, E. (PI)
EPSRC
1/06/15 → 30/09/19
Project: Standard

A Luminescent 1D Silver Polymer Containing [2.2]Paracyclophane Ligands (dataset)
Mackenzie, C. F. R. (Creator), Delforce, L. (Creator), Rota Martir, D. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator) & Zysman-Colman, E. (Creator), University of St Andrews, 27 Jul 2021
DOI: 10.17630/9e0d4b83-171a-4805-aef8-a9fbac035c1f
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Cite this

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title = "A luminescent 1D silver polymer containing [2.2]paracyclophane ligands",

abstract = "[2.2]Paracyclophane scaffolds have seen limited use as building blocks in supramolecular chemistry. Here, we report the synthesis and characterization of a 1D coordination polymer consisting of silver(I) ions bound to a [2.2]paracyclophane scaffold functionalized with two 4-pyridyl units. The structure of the polymer has been determined from single crystal X-ray diffraction analysis and reveals two different silver coordination motifs that alternate along the 1D coordination polymer. The coordination polymer exhibits strong blue and sky-blue fluorescence in solution and in the crystalline solid state, respectively. ",

keywords = "Coordination polymer, Cyclophane, Supramolecular chemistry, Silver",

author = "Mackenzie, {Campbell F. R.} and Lucie Delforce and {Rota Martir}, D. and Cordes, {David B.} and Slawin, {Alexandra M. Z.} and Eli Zysman-Colman",

note = "Funding: UK EPSRC Grant Number(s) EP/P014082/1, EP/M02105X/1, EP/R035164/1).",

year = "2021",

month = aug,

day = "2",

doi = "10.3389/fchem.2021.728845",

language = "English",

volume = "9",

journal = "Frontiers in Chemistry",

issn = "2296-2646",

publisher = "Frontiers Media S. A.",

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TY - JOUR

T1 - A luminescent 1D silver polymer containing [2.2]paracyclophane ligands

AU - Mackenzie, Campbell F. R.

AU - Delforce, Lucie

AU - Rota Martir, D.

AU - Cordes, David B.

AU - Slawin, Alexandra M. Z.

AU - Zysman-Colman, Eli

N1 - Funding: UK EPSRC Grant Number(s) EP/P014082/1, EP/M02105X/1, EP/R035164/1).

PY - 2021/8/2

Y1 - 2021/8/2

N2 - [2.2]Paracyclophane scaffolds have seen limited use as building blocks in supramolecular chemistry. Here, we report the synthesis and characterization of a 1D coordination polymer consisting of silver(I) ions bound to a [2.2]paracyclophane scaffold functionalized with two 4-pyridyl units. The structure of the polymer has been determined from single crystal X-ray diffraction analysis and reveals two different silver coordination motifs that alternate along the 1D coordination polymer. The coordination polymer exhibits strong blue and sky-blue fluorescence in solution and in the crystalline solid state, respectively.

AB - [2.2]Paracyclophane scaffolds have seen limited use as building blocks in supramolecular chemistry. Here, we report the synthesis and characterization of a 1D coordination polymer consisting of silver(I) ions bound to a [2.2]paracyclophane scaffold functionalized with two 4-pyridyl units. The structure of the polymer has been determined from single crystal X-ray diffraction analysis and reveals two different silver coordination motifs that alternate along the 1D coordination polymer. The coordination polymer exhibits strong blue and sky-blue fluorescence in solution and in the crystalline solid state, respectively.

KW - Coordination polymer

KW - Cyclophane

KW - Supramolecular chemistry

KW - Silver

U2 - 10.3389/fchem.2021.728845

DO - 10.3389/fchem.2021.728845

M3 - Article

SN - 2296-2646

VL - 9

JO - Frontiers in Chemistry

JF - Frontiers in Chemistry

M1 - 728845

ER -

A luminescent 1D silver polymer containing [2.2]paracyclophane ligands

Abstract

Keywords

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Projects

Chemistry EPSRC-JSPS: EPSRC-JSPS Core-to-Core Grant Application

Blue-Emitting Phospors: Blue-emitting Phosphors for Solid State Lighting Applications

Datasets

A Luminescent 1D Silver Polymer Containing [2.2]Paracyclophane Ligands (dataset)

Cite this