A hydrogen-bonded adduct containing seven-component supramolecular aggregates

C J  Burchell; G  Ferguson; A J  Lough; C  Glidewell

doi:10.1107/S0108270100013792

A hydrogen-bonded adduct containing seven-component supramolecular aggregates

C J Burchell, G Ferguson, A J Lough, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound is a salt, 3,6,9,16,19,22-hexaazatricyclo[22.2.2.2(11,14)]triaconta-1(26),11(29),12,14(30),24,27-hexaene-3,5-dinitrobenzoic acid-methanol (1/4/2), C24H42N64+. -4C(7)H(3)N(2)O(6)(-). 2CH(4)O, in which the cation lies across a centre of inversion and one of the two independent anions is positionally disordered over two sets of atom sites having equal occupancy. The components are linked by four types of N-H . . .O hydrogen bond [N . . .O 2.674 (2)-2.815 (2) Angstrom; N-H . . .O 149-163 degrees] and one type of O-H . . .O hydrogen bond in which the acceptor is disordered over two closely adjacent sites [O . . .O 2.67 (4) and 2.75 (4) Angstrom; O-H . . .O 172 and 173 degrees], forming centrosymmetric seven-component aggregates.

Original language	English
Pages (from-to)	88-91
Number of pages	4
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	57
Issue number	1
DOIs	https://doi.org/10.1107/S0108270100013792
Publication status	Published - Jan 2001

Keywords

COMPLEXES

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10.1107/S0108270100013792

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title = "A hydrogen-bonded adduct containing seven-component supramolecular aggregates",

abstract = "The title compound is a salt, 3,6,9,16,19,22-hexaazatricyclo[22.2.2.2(11,14)]triaconta-1(26),11(29),12,14(30),24,27-hexaene-3,5-dinitrobenzoic acid-methanol (1/4/2), C24H42N64+. -4C(7)H(3)N(2)O(6)(-). 2CH(4)O, in which the cation lies across a centre of inversion and one of the two independent anions is positionally disordered over two sets of atom sites having equal occupancy. The components are linked by four types of N-H . . .O hydrogen bond [N . . .O 2.674 (2)-2.815 (2) Angstrom; N-H . . .O 149-163 degrees] and one type of O-H . . .O hydrogen bond in which the acceptor is disordered over two closely adjacent sites [O . . .O 2.67 (4) and 2.75 (4) Angstrom; O-H . . .O 172 and 173 degrees], forming centrosymmetric seven-component aggregates.",

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author = "Burchell, {C J} and G Ferguson and Lough, {A J} and C Glidewell",

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T1 - A hydrogen-bonded adduct containing seven-component supramolecular aggregates

AU - Burchell, C J

AU - Ferguson, G

AU - Lough, A J

AU - Glidewell, C

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Y1 - 2001/1

N2 - The title compound is a salt, 3,6,9,16,19,22-hexaazatricyclo[22.2.2.2(11,14)]triaconta-1(26),11(29),12,14(30),24,27-hexaene-3,5-dinitrobenzoic acid-methanol (1/4/2), C24H42N64+. -4C(7)H(3)N(2)O(6)(-). 2CH(4)O, in which the cation lies across a centre of inversion and one of the two independent anions is positionally disordered over two sets of atom sites having equal occupancy. The components are linked by four types of N-H . . .O hydrogen bond [N . . .O 2.674 (2)-2.815 (2) Angstrom; N-H . . .O 149-163 degrees] and one type of O-H . . .O hydrogen bond in which the acceptor is disordered over two closely adjacent sites [O . . .O 2.67 (4) and 2.75 (4) Angstrom; O-H . . .O 172 and 173 degrees], forming centrosymmetric seven-component aggregates.

AB - The title compound is a salt, 3,6,9,16,19,22-hexaazatricyclo[22.2.2.2(11,14)]triaconta-1(26),11(29),12,14(30),24,27-hexaene-3,5-dinitrobenzoic acid-methanol (1/4/2), C24H42N64+. -4C(7)H(3)N(2)O(6)(-). 2CH(4)O, in which the cation lies across a centre of inversion and one of the two independent anions is positionally disordered over two sets of atom sites having equal occupancy. The components are linked by four types of N-H . . .O hydrogen bond [N . . .O 2.674 (2)-2.815 (2) Angstrom; N-H . . .O 149-163 degrees] and one type of O-H . . .O hydrogen bond in which the acceptor is disordered over two closely adjacent sites [O . . .O 2.67 (4) and 2.75 (4) Angstrom; O-H . . .O 172 and 173 degrees], forming centrosymmetric seven-component aggregates.

KW - COMPLEXES

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DO - 10.1107/S0108270100013792

M3 - Article

SN - 0108-2701

VL - 57

SP - 88

EP - 91

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 1

ER -

A hydrogen-bonded adduct containing seven-component supramolecular aggregates

Abstract

Keywords

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