A hybrid vanadium fluoride with structurally isolated S=1 kagome layers

Farida H. Aidoudi; Lewis J. Downie; Russell E. Morris; Mark A. de Vries; Philip Lightfoot

doi:10.1039/c4dt00452c

A hybrid vanadium fluoride with structurally isolated S=1 kagome layers

Farida H. Aidoudi, Lewis J. Downie, Russell E. Morris, Mark A. de Vries, Philip Lightfoot^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A new organically-templated vanadium(III) fluoride, (NH4)(2)( C2H8N)-[ V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling in the ground state a pronounced change in magnetisation kinetics is observed.

Original language	English
Pages (from-to)	6304-6307
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	17
Early online date	13 Feb 2014
DOIs	https://doi.org/10.1039/c4dt00452c
Publication status	Published - 2014

Keywords

Magnetic-properties
Oxyfluorides
Lattice
Temperature
Compound

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10.1039/c4dt00452c

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© 2013 The Authors.
Accepted author manuscript, 1.64 MB

Cite this

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title = "A hybrid vanadium fluoride with structurally isolated S=1 kagome layers",

abstract = "A new organically-templated vanadium(III) fluoride, (NH4)(2)( C2H8N)-[ V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling in the ground state a pronounced change in magnetisation kinetics is observed.",

keywords = "Magnetic-properties, Oxyfluorides, Lattice, Temperature, Compound",

author = "Aidoudi, {Farida H.} and Downie, {Lewis J.} and Morris, {Russell E.} and {de Vries}, {Mark A.} and Philip Lightfoot",

note = "Funding: EPSRC Doctoral Prize Fellowship (FHA), Royal Society (REM), US Department of Energy contract no. E-AC02-05CH11231 (ALS).",

year = "2014",

doi = "10.1039/c4dt00452c",

language = "English",

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journal = "Dalton Transactions",

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T1 - A hybrid vanadium fluoride with structurally isolated S=1 kagome layers

AU - Aidoudi, Farida H.

AU - Downie, Lewis J.

AU - Morris, Russell E.

AU - de Vries, Mark A.

AU - Lightfoot, Philip

N1 - Funding: EPSRC Doctoral Prize Fellowship (FHA), Royal Society (REM), US Department of Energy contract no. E-AC02-05CH11231 (ALS).

PY - 2014

Y1 - 2014

N2 - A new organically-templated vanadium(III) fluoride, (NH4)(2)( C2H8N)-[ V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling in the ground state a pronounced change in magnetisation kinetics is observed.

AB - A new organically-templated vanadium(III) fluoride, (NH4)(2)( C2H8N)-[ V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling in the ground state a pronounced change in magnetisation kinetics is observed.

KW - Magnetic-properties

KW - Oxyfluorides

KW - Lattice

KW - Temperature

KW - Compound

U2 - 10.1039/c4dt00452c

DO - 10.1039/c4dt00452c

M3 - Article

SN - 1477-9226

VL - 43

SP - 6304

EP - 6307

JO - Dalton Transactions

JF - Dalton Transactions

IS - 17

ER -

A hybrid vanadium fluoride with structurally isolated S=1 kagome layers

Abstract

Keywords

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