A highly reactive rhodium(I)-boryl complex as a useful tool for C-H bond activation and catalytic C-F bond borylation

Michael Teltewskoi; Julien A. Panetier; Stuart A. Macgregor; Thomas Braun

doi:10.1002/anie.201001070

A highly reactive rhodium(I)-boryl complex as a useful tool for C-H bond activation and catalytic C-F bond borylation

Michael Teltewskoi^*
, Julien A. Panetier
, Stuart A. Macgregor
, Thomas Braun

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Chemical Equation Presentation C-F bond borylation: A 16-electron rhodium (1)-boryl complex was synthesized by borylation of a rhodium (1)-fluorine complex. The former reacts with benzene or 2,3,5,6-tetrafluoropyridine by C-H activation. A catalytic C-F borylation reaction of pentafluoropyridine was also developed, which uses [Rh(Bpin) (PEt₃)₃] as a catalyst and Me₃SiSiMe₃ as a solvent. pin = pinacol.

Original language	English
Pages (from-to)	3947-3951
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	23
DOIs	https://doi.org/10.1002/anie.201001070
Publication status	Published - 25 May 2010

Keywords

Boryl ligands
Borylation
C-F activation
C-H activation
Rhodium

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title = "A highly reactive rhodium(I)-boryl complex as a useful tool for C-H bond activation and catalytic C-F bond borylation",

abstract = "Chemical Equation Presentation C-F bond borylation: A 16-electron rhodium (1)-boryl complex was synthesized by borylation of a rhodium (1)-fluorine complex. The former reacts with benzene or 2,3,5,6-tetrafluoropyridine by C-H activation. A catalytic C-F borylation reaction of pentafluoropyridine was also developed, which uses [Rh(Bpin) (PEt3)3] as a catalyst and Me3SiSiMe3 as a solvent. pin = pinacol.",

keywords = "Boryl ligands, Borylation, C-F activation, C-H activation, Rhodium",

author = "Michael Teltewskoi and Panetier, \{Julien A.\} and Macgregor, \{Stuart A.\} and Thomas Braun",

year = "2010",

month = may,

day = "25",

doi = "10.1002/anie.201001070",

language = "English",

volume = "49",

pages = "3947--3951",

journal = "Angewandte Chemie - International Edition",

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publisher = "John Wiley \& Sons, Ltd",

number = "23",

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TY - JOUR

T1 - A highly reactive rhodium(I)-boryl complex as a useful tool for C-H bond activation and catalytic C-F bond borylation

AU - Teltewskoi, Michael

AU - Panetier, Julien A.

AU - Macgregor, Stuart A.

AU - Braun, Thomas

PY - 2010/5/25

Y1 - 2010/5/25

N2 - Chemical Equation Presentation C-F bond borylation: A 16-electron rhodium (1)-boryl complex was synthesized by borylation of a rhodium (1)-fluorine complex. The former reacts with benzene or 2,3,5,6-tetrafluoropyridine by C-H activation. A catalytic C-F borylation reaction of pentafluoropyridine was also developed, which uses [Rh(Bpin) (PEt3)3] as a catalyst and Me3SiSiMe3 as a solvent. pin = pinacol.

AB - Chemical Equation Presentation C-F bond borylation: A 16-electron rhodium (1)-boryl complex was synthesized by borylation of a rhodium (1)-fluorine complex. The former reacts with benzene or 2,3,5,6-tetrafluoropyridine by C-H activation. A catalytic C-F borylation reaction of pentafluoropyridine was also developed, which uses [Rh(Bpin) (PEt3)3] as a catalyst and Me3SiSiMe3 as a solvent. pin = pinacol.

KW - Boryl ligands

KW - Borylation

KW - C-F activation

KW - C-H activation

KW - Rhodium

UR - https://www.scopus.com/pages/publications/77953005519

U2 - 10.1002/anie.201001070

DO - 10.1002/anie.201001070

M3 - Article

AN - SCOPUS:77953005519

SN - 1433-7851

VL - 49

SP - 3947

EP - 3951

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 23

ER -

A highly reactive rhodium(I)-boryl complex as a useful tool for C-H bond activation and catalytic C-F bond borylation

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Keywords

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