A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

Orlando Santoro; Alba Collado-Martinez; Alexandra Martha Zoya Slawin; Steven Patrick Nolan; Catherine S.J. Cazin

doi:10.1039/c3cc45488f

A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

Orlando Santoro
, Alba Collado-Martinez
, Alexandra Martha Zoya Slawin
, Steven Patrick Nolan
, Catherine S.J. Cazin

Research output: Contribution to journal › Article › peer-review

Abstract

A one-pot procedure for the synthesis of [Cu(X)(NHC)] (X = Cl, Br, I) is reported. The reaction is applicable to a wide range of saturated and unsaturated NHC ligands, is scalable and proceeds under mild conditions using technical grade solvents in air.

Original language	English
Pages (from-to)	10483-10485
Number of pages	3
Journal	Chemical Communications
Volume	49
Early online date	1 Oct 2013
DOIs	https://doi.org/10.1039/c3cc45488f
Publication status	Published - 2013

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10.1039/c3cc45488f

santoro2013chemcomm10483
© 2012. The Royal Society of Chemistry. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
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Copper(I)-N-heterocyclic carbene (NHC) complexes: synthesis, characterisation and applications in synthesis and catalysis
Santoro, O. (Author), Cazin, C. S. J. (Supervisor), 22 Jun 2016
Student thesis: Doctoral Thesis (PhD)

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@article{56e48e07dde540e992e92cf42186164a,

title = "A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes",

abstract = "A one-pot procedure for the synthesis of [Cu(X)(NHC)] (X = Cl, Br, I) is reported. The reaction is applicable to a wide range of saturated and unsaturated NHC ligands, is scalable and proceeds under mild conditions using technical grade solvents in air.",

author = "Orlando Santoro and Alba Collado-Martinez and Slawin, \{Alexandra Martha Zoya\} and Nolan, \{Steven Patrick\} and Cazin, \{Catherine S.J.\}",

year = "2013",

doi = "10.1039/c3cc45488f",

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volume = "49",

pages = "10483--10485",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

AU - Santoro, Orlando

AU - Collado-Martinez, Alba

AU - Slawin, Alexandra Martha Zoya

AU - Nolan, Steven Patrick

AU - Cazin, Catherine S.J.

PY - 2013

Y1 - 2013

N2 - A one-pot procedure for the synthesis of [Cu(X)(NHC)] (X = Cl, Br, I) is reported. The reaction is applicable to a wide range of saturated and unsaturated NHC ligands, is scalable and proceeds under mild conditions using technical grade solvents in air.

AB - A one-pot procedure for the synthesis of [Cu(X)(NHC)] (X = Cl, Br, I) is reported. The reaction is applicable to a wide range of saturated and unsaturated NHC ligands, is scalable and proceeds under mild conditions using technical grade solvents in air.

U2 - 10.1039/c3cc45488f

DO - 10.1039/c3cc45488f

M3 - Article

SN - 1359-7345

VL - 49

SP - 10483

EP - 10485

JO - Chemical Communications

JF - Chemical Communications

ER -

A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

Abstract

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Student theses

Copper(I)-N-heterocyclic carbene (NHC) complexes: synthesis, characterisation and applications in synthesis and catalysis

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