TY - JOUR
T1 - A family of [Ni8] cages templated by μ6-peroxide from dioxygen activation
AU - Perivolaris, Alexandros
AU - Stoumpos, Constantinos C.
AU - Karpinska, Jolanta
AU - Ryder, Alan G.
AU - Frost, Jamie M.
AU - Mason, Kevin
AU - Prescimone, Alessandro
AU - Slawin, Alexandra M Z
AU - Kessler, Vadim G.
AU - Mathieson, Jennifer S.
AU - Cronin, Leroy
AU - Brechin, Euan K.
AU - Papaefstathiou, Giannis S.
PY - 2014/6/1
Y1 - 2014/6/1
N2 - A family of exceptionally thermally stable [Ni8] cages is reported, each being templated by a rare η3:η3:μ6-O2 2- species produced by dioxygen activation, where the reducing agent for the O2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.
AB - A family of exceptionally thermally stable [Ni8] cages is reported, each being templated by a rare η3:η3:μ6-O2 2- species produced by dioxygen activation, where the reducing agent for the O2 reduction appears to be the ligand used in the reaction mixtures, which was found within the nickel cages in its oxidized form.
UR - http://www.scopus.com/inward/record.url?scp=84946730096&partnerID=8YFLogxK
U2 - 10.1039/c4qi00048j
DO - 10.1039/c4qi00048j
M3 - Article
AN - SCOPUS:84946730096
SN - 2052-1545
VL - 1
SP - 487
EP - 494
JO - Inorganic Chemistry Frontiers
JF - Inorganic Chemistry Frontiers
IS - 6
ER -