A facile synthesis of a push-pull mixed-ligand Pd-dithiolene complex containing the Et2timdt ligand (Et2timdt = monoreduced diethylimidazolidine-2,4,5-trithione

MC Aragoni; M Arca; C Denotti; FA Devillanova; E Grigiotti; F Isaia; F Laschi; V Lippolis; L Pala; Alexandra Martha Zoya Slawin; P Zanello; John Derek Woollins

A facile synthesis of a push-pull mixed-ligand Pd-dithiolene complex containing the Et₂timdt ligand (Et₂timdt = monoreduced diethylimidazolidine-2,4,5-trithione

MC Aragoni, M Arca, C Denotti, FA Devillanova, E Grigiotti, F Isaia, F Laschi, V Lippolis, L Pala, Alexandra Martha Zoya Slawin, P Zanello, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The reaction of the dithiolene [Pd(Et(2)timdt)(2)] (Et(2)timdt = formally monoreduced diethylimidazolidine-2,4,5-trithione) with Br-2 or IBr yields the complex [Pd(Et(2)timdt)Br-2], a good starting material for the synthesis of novel push-pull mixed-ligand Pd-dithiolenes. The synthesis and characterisation of the unsymmetrical dithiolene [Pd(Et(2)timdt)(mnt)] (mnt = maleonitriledithiolato dianion) is also reported. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

Original language	English
Pages (from-to)	1291-1295
Number of pages	5
Journal	European Journal of Inorganic Chemistry
Publication status	Published - Apr 2003

Keywords

palladium
halogenation
S ligands
density functional calculations
nonlinear optics
NEAR-IR ABSORPTION
SPECTROSCOPIC PROPERTIES
CRYSTAL-STRUCTURE
METAL-COMPLEXES
MONOANION
EXCHANGE
BEHAVIOR
DMIT
NI

Cite this

Aragoni, MC., Arca, M., Denotti, C., Devillanova, FA., Grigiotti, E., Isaia, F., Laschi, F., Lippolis, V., Pala, L., Slawin, A. M. Z., Zanello, P., & Woollins, J. D. (2003). A facile synthesis of a push-pull mixed-ligand Pd-dithiolene complex containing the Et₂timdt ligand (Et₂timdt = monoreduced diethylimidazolidine-2,4,5-trithione. European Journal of Inorganic Chemistry, 1291-1295.

@article{d05974e355ab4969bd15626263c3fd8e,

title = "A facile synthesis of a push-pull mixed-ligand Pd-dithiolene complex containing the Et2timdt ligand (Et2timdt = monoreduced diethylimidazolidine-2,4,5-trithione",

abstract = "The reaction of the dithiolene [Pd(Et(2)timdt)(2)] (Et(2)timdt = formally monoreduced diethylimidazolidine-2,4,5-trithione) with Br-2 or IBr yields the complex [Pd(Et(2)timdt)Br-2], a good starting material for the synthesis of novel push-pull mixed-ligand Pd-dithiolenes. The synthesis and characterisation of the unsymmetrical dithiolene [Pd(Et(2)timdt)(mnt)] (mnt = maleonitriledithiolato dianion) is also reported. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).",

keywords = "palladium, halogenation, S ligands, density functional calculations, nonlinear optics, NEAR-IR ABSORPTION, SPECTROSCOPIC PROPERTIES, CRYSTAL-STRUCTURE, METAL-COMPLEXES, MONOANION, EXCHANGE, BEHAVIOR, DMIT, NI",

author = "MC Aragoni and M Arca and C Denotti and FA Devillanova and E Grigiotti and F Isaia and F Laschi and V Lippolis and L Pala and Slawin, {Alexandra Martha Zoya} and P Zanello and Woollins, {John Derek}",

year = "2003",

month = apr,

language = "English",

pages = "1291--1295",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-Blackwell",

}

Aragoni, MC, Arca, M, Denotti, C, Devillanova, FA, Grigiotti, E, Isaia, F, Laschi, F, Lippolis, V, Pala, L, Slawin, AMZ, Zanello, P & Woollins, JD 2003, 'A facile synthesis of a push-pull mixed-ligand Pd-dithiolene complex containing the Et₂timdt ligand (Et₂timdt = monoreduced diethylimidazolidine-2,4,5-trithione', European Journal of Inorganic Chemistry, pp. 1291-1295.

TY - JOUR

T1 - A facile synthesis of a push-pull mixed-ligand Pd-dithiolene complex containing the Et2timdt ligand (Et2timdt = monoreduced diethylimidazolidine-2,4,5-trithione

AU - Aragoni, MC

AU - Arca, M

AU - Denotti, C

AU - Devillanova, FA

AU - Grigiotti, E

AU - Isaia, F

AU - Laschi, F

AU - Lippolis, V

AU - Pala, L

AU - Slawin, Alexandra Martha Zoya

AU - Zanello, P

AU - Woollins, John Derek

PY - 2003/4

Y1 - 2003/4

N2 - The reaction of the dithiolene [Pd(Et(2)timdt)(2)] (Et(2)timdt = formally monoreduced diethylimidazolidine-2,4,5-trithione) with Br-2 or IBr yields the complex [Pd(Et(2)timdt)Br-2], a good starting material for the synthesis of novel push-pull mixed-ligand Pd-dithiolenes. The synthesis and characterisation of the unsymmetrical dithiolene [Pd(Et(2)timdt)(mnt)] (mnt = maleonitriledithiolato dianion) is also reported. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

AB - The reaction of the dithiolene [Pd(Et(2)timdt)(2)] (Et(2)timdt = formally monoreduced diethylimidazolidine-2,4,5-trithione) with Br-2 or IBr yields the complex [Pd(Et(2)timdt)Br-2], a good starting material for the synthesis of novel push-pull mixed-ligand Pd-dithiolenes. The synthesis and characterisation of the unsymmetrical dithiolene [Pd(Et(2)timdt)(mnt)] (mnt = maleonitriledithiolato dianion) is also reported. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

KW - palladium

KW - halogenation

KW - S ligands

KW - density functional calculations

KW - nonlinear optics

KW - NEAR-IR ABSORPTION

KW - SPECTROSCOPIC PROPERTIES

KW - CRYSTAL-STRUCTURE

KW - METAL-COMPLEXES

KW - MONOANION

KW - EXCHANGE

KW - BEHAVIOR

KW - DMIT

KW - NI

UR - http://www.scopus.com/inward/record.url?scp=0037395049&partnerID=8YFLogxK

M3 - Article

SN - 1434-1948

SP - 1291

EP - 1295

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

ER -

A facile synthesis of a push-pull mixed-ligand Pd-dithiolene complex containing the Et₂timdt ligand (Et₂timdt = monoreduced diethylimidazolidine-2,4,5-trithione

Abstract

Keywords

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