A continuous process concept for homogeneous catalysis in fluorous biphasic systems

E  Perperi; Y L  Huang; P  Angeli; G  Manos; C R  Mathison; D J  Cole-Hamilton; D A  Adams; E G  Hope

doi:10.1016/j.ces.2004.08.045

A continuous process concept for homogeneous catalysis in fluorous biphasic systems

E Perperi, Y L Huang, P Angeli, G Manos, C R Mathison, D J Cole-Hamilton, D A Adams, E G Hope

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

A novel continuous homogeneous catalytic system for the long-term testing of hydroformylation in fluorous biphasic systems has been developed. Conversion levels up to 70 % were observed, with linear to branched product ratios being around 12, while the fluorous catalyst was successfully recycled to the reactor. Efficient stirring is essential for high conversions for minimising alkene isomerisation. Leaching of the ligand, rhodium and the fluorous solvent into the organic product phase are significant. (C) 2004 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	4983-4989
Number of pages	7
Journal	Chemical Engineering Science
Volume	59
DOIs	https://doi.org/10.1016/j.ces.2004.08.045
Publication status	Published - Nov 2004

Keywords

homogeneous catalysis
liquid-liquid separation
octene
phase behaviour
fluorous biphasic system
hydroformylation
HIGHER OLEFINS
SEPARATION TECHNIQUES
SUPERCRITICAL CO2
HYDROFORMYLATION
ALKENES
COMPLEXES
SOLVENTS
LIGANDS
DESIGN
WATER

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10.1016/j.ces.2004.08.045

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abstract = "A novel continuous homogeneous catalytic system for the long-term testing of hydroformylation in fluorous biphasic systems has been developed. Conversion levels up to 70 % were observed, with linear to branched product ratios being around 12, while the fluorous catalyst was successfully recycled to the reactor. Efficient stirring is essential for high conversions for minimising alkene isomerisation. Leaching of the ligand, rhodium and the fluorous solvent into the organic product phase are significant. (C) 2004 Elsevier Ltd. All rights reserved.",

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language = "English",

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journal = "Chemical Engineering Science",

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AU - Perperi, E

AU - Huang, Y L

AU - Angeli, P

AU - Manos, G

AU - Mathison, C R

AU - Cole-Hamilton, D J

AU - Adams, D A

AU - Hope, E G

PY - 2004/11

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KW - homogeneous catalysis

KW - liquid-liquid separation

KW - octene

KW - phase behaviour

KW - fluorous biphasic system

KW - hydroformylation

KW - HIGHER OLEFINS

KW - SEPARATION TECHNIQUES

KW - SUPERCRITICAL CO2

KW - HYDROFORMYLATION

KW - ALKENES

KW - COMPLEXES

KW - SOLVENTS

KW - LIGANDS

KW - DESIGN

KW - WATER

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DO - 10.1016/j.ces.2004.08.045

M3 - Article

VL - 59

SP - 4983

EP - 4989

JO - Chemical Engineering Science

JF - Chemical Engineering Science

ER -

A continuous process concept for homogeneous catalysis in fluorous biphasic systems

Abstract

Keywords

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