Abstract
Substituted indenes can be prepared after a sequence [1,3] O-acyl shift-hydroarylation-[1,3] O-acyl shift. Each step is catalyzed by a cationic NHC-Gold(I) species generated in situ after reaction between [(IPr) AuOH] and HBF4 center dot OEt2. This interesting silver-free way is fully supported by a computational study justifying the formation of each intermediate.
| Original language | English |
|---|---|
| Pages (from-to) | 101-104 |
| Number of pages | 4 |
| Journal | Organic & Biomolecular Chemistry |
| Volume | 9 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 2011 |
Keywords
- N-HETEROCYCLIC CARBENES
- GOLD CATALYSIS
- PROPARGYLIC ACETATES
- PLATINUM
- APPROXIMATION
- REARRANGEMENT
- ACTIVATION
- DIVERSITY
- SOLVENT
- ALKYNES
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Dive into the research topics of 'A combined mechanistic and computational study of the gold(I)-catalyzed formation of substituted indenes'. Together they form a unique fingerprint.Projects
- 1 Finished
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Molecular assembly using gold catalysis: Molecular assembly using gold catalysis
Nolan, S. (PI)
1/01/10 → 31/12/12
Project: Standard
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