A chain of fused R-2(2)(10) and R-6(4)(12) rings in the hydrogen-bonded structure of 1,4,8,11-tetraazacyclotetradecane-2,2 '-biphenol (1/2)

G  Ferguson; R M  Gregson; C  Glidewell

A chain of fused R-2(2)(10) and R-6(4)(12) rings in the hydrogen-bonded structure of 1,4,8,11-tetraazacyclotetradecane-2,2 '-biphenol (1/2)

G Ferguson, R M Gregson, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound is a salt, i.e. 4,11-diaza-1,8-diazoniacyclotetradecane bis[2(2-hydroxyphenyl)phenolate], C10H26N42+.2HOC(6)H(4)C(6)H(4)O(-). The centrosymmetric cation contains two intramolecular N-H...N hydrogen bonds, with an N...N distance of 2.865 (2) Angstrom, and the anion contains an intramolecular O-H...O hydrogen bond, with an O...O distance of 2.486 (2) Angstrom. The ions are linked into continuous chains by means of two types of N-H...O hydrogen bond having N...O distances of 2.682(2) and 3.273 (2) Angstrom.

Original language	English
Pages (from-to)	815-817
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	55
Publication status	Published - 15 May 1999

Keywords

ADDUCTS
CYCLAM
SYSTEM

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title = "A chain of fused R-2(2)(10) and R-6(4)(12) rings in the hydrogen-bonded structure of 1,4,8,11-tetraazacyclotetradecane-2,2 '-biphenol (1/2)",

abstract = "The title compound is a salt, i.e. 4,11-diaza-1,8-diazoniacyclotetradecane bis[2(2-hydroxyphenyl)phenolate], C10H26N42+.2HOC(6)H(4)C(6)H(4)O(-). The centrosymmetric cation contains two intramolecular N-H...N hydrogen bonds, with an N...N distance of 2.865 (2) Angstrom, and the anion contains an intramolecular O-H...O hydrogen bond, with an O...O distance of 2.486 (2) Angstrom. The ions are linked into continuous chains by means of two types of N-H...O hydrogen bond having N...O distances of 2.682(2) and 3.273 (2) Angstrom.",

keywords = "ADDUCTS, CYCLAM, SYSTEM",

author = "G Ferguson and Gregson, {R M} and C Glidewell",

year = "1999",

month = may,

day = "15",

language = "English",

volume = "55",

pages = "815--817",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - A chain of fused R-2(2)(10) and R-6(4)(12) rings in the hydrogen-bonded structure of 1,4,8,11-tetraazacyclotetradecane-2,2 '-biphenol (1/2)

AU - Ferguson, G

AU - Gregson, R M

AU - Glidewell, C

PY - 1999/5/15

Y1 - 1999/5/15

N2 - The title compound is a salt, i.e. 4,11-diaza-1,8-diazoniacyclotetradecane bis[2(2-hydroxyphenyl)phenolate], C10H26N42+.2HOC(6)H(4)C(6)H(4)O(-). The centrosymmetric cation contains two intramolecular N-H...N hydrogen bonds, with an N...N distance of 2.865 (2) Angstrom, and the anion contains an intramolecular O-H...O hydrogen bond, with an O...O distance of 2.486 (2) Angstrom. The ions are linked into continuous chains by means of two types of N-H...O hydrogen bond having N...O distances of 2.682(2) and 3.273 (2) Angstrom.

AB - The title compound is a salt, i.e. 4,11-diaza-1,8-diazoniacyclotetradecane bis[2(2-hydroxyphenyl)phenolate], C10H26N42+.2HOC(6)H(4)C(6)H(4)O(-). The centrosymmetric cation contains two intramolecular N-H...N hydrogen bonds, with an N...N distance of 2.865 (2) Angstrom, and the anion contains an intramolecular O-H...O hydrogen bond, with an O...O distance of 2.486 (2) Angstrom. The ions are linked into continuous chains by means of two types of N-H...O hydrogen bond having N...O distances of 2.682(2) and 3.273 (2) Angstrom.

KW - ADDUCTS

KW - CYCLAM

KW - SYSTEM

M3 - Article

SN - 1600-5759

VL - 55

SP - 815

EP - 817

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

A chain of fused R-2(2)(10) and R-6(4)(12) rings in the hydrogen-bonded structure of 1,4,8,11-tetraazacyclotetradecane-2,2 '-biphenol (1/2)

Abstract

Keywords

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