A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst

H M  Lee; T  Jiang; E D  Stevens; Steven Patrick Nolan

doi:10.1021/om000990x

A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst

H M Lee, T Jiang, E D Stevens, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

171 Citations (Scopus)

Abstract

The new cationic iridium carbene complex [Ir(cod)(py)(SIMes)]PF6 (2) has been synthesized by reaction of [Ir(cod)(py)(2)]PF6 with SIMes. Complex 2 is an active hydrogenation catalyst capable of hydrogenating simple olefins at roam temperature and atmospheric pressure of hydrogen.

Original language	English
Pages (from-to)	1255-1258
Number of pages	4
Journal	Organometallics
Volume	20
Issue number	6
DOIs	https://doi.org/10.1021/om000990x
Publication status	Published - 19 Mar 2001

Keywords

PALLADIUM/IMIDAZOLIUM CHLORIDE SYSTEM
OLEFIN METATHESIS CATALYSTS
STABLE CARBENES
ARYL CHLORIDES
HOMOGENEOUS HYDROGENATION
DIOLEFIN COMPLEXES
RUTHENIUM

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title = "A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst",

abstract = "The new cationic iridium carbene complex [Ir(cod)(py)(SIMes)]PF6 (2) has been synthesized by reaction of [Ir(cod)(py)(2)]PF6 with SIMes. Complex 2 is an active hydrogenation catalyst capable of hydrogenating simple olefins at roam temperature and atmospheric pressure of hydrogen.",

keywords = "PALLADIUM/IMIDAZOLIUM CHLORIDE SYSTEM, OLEFIN METATHESIS CATALYSTS, STABLE CARBENES, ARYL CHLORIDES, HOMOGENEOUS HYDROGENATION, DIOLEFIN COMPLEXES, RUTHENIUM",

author = "Lee, {H M} and T Jiang and Stevens, {E D} and Nolan, {Steven Patrick}",

year = "2001",

month = mar,

day = "19",

doi = "10.1021/om000990x",

language = "English",

volume = "20",

pages = "1255--1258",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society (ACS)",

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TY - JOUR

T1 - A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst

AU - Lee, H M

AU - Jiang, T

AU - Stevens, E D

AU - Nolan, Steven Patrick

PY - 2001/3/19

Y1 - 2001/3/19

N2 - The new cationic iridium carbene complex [Ir(cod)(py)(SIMes)]PF6 (2) has been synthesized by reaction of [Ir(cod)(py)(2)]PF6 with SIMes. Complex 2 is an active hydrogenation catalyst capable of hydrogenating simple olefins at roam temperature and atmospheric pressure of hydrogen.

AB - The new cationic iridium carbene complex [Ir(cod)(py)(SIMes)]PF6 (2) has been synthesized by reaction of [Ir(cod)(py)(2)]PF6 with SIMes. Complex 2 is an active hydrogenation catalyst capable of hydrogenating simple olefins at roam temperature and atmospheric pressure of hydrogen.

KW - PALLADIUM/IMIDAZOLIUM CHLORIDE SYSTEM

KW - OLEFIN METATHESIS CATALYSTS

KW - STABLE CARBENES

KW - ARYL CHLORIDES

KW - HOMOGENEOUS HYDROGENATION

KW - DIOLEFIN COMPLEXES

KW - RUTHENIUM

U2 - 10.1021/om000990x

DO - 10.1021/om000990x

M3 - Article

SN - 0276-7333

VL - 20

SP - 1255

EP - 1258

JO - Organometallics

JF - Organometallics

IS - 6

ER -

A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst

Abstract

Keywords

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