8-Bromonaphthalen-1-amine

Amy L. Fuller, Fergus R. Knight, Alexandra M. Z. Slawin, J. Derek Woollins

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

The title compound, C10H8BrN, was obtained by slow addition of sodium azide to 8-bromo-1-naphthoic acid, followed by addition of aqueous ammonia. The crude product was crystallized from petroleum ether to give pink crystals. Compared to other 1,8-disubstituted naphthalene compounds, this compound exhibits less strain between the 1 and 8 substituents. Additionally, the NH protons form both intra- and intermolecular hydrogen bonds. The naphthalene units are arranged in a herring-bone stacking motif.

Original languageEnglish
Number of pages9
JournalActa Crystallographica. Section E, Structure reports online
Volume64
DOIs
Publication statusPublished - Jun 2008

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