6-Amino-3-methyl-5-nitrosopyrimidine-2,4(1H,3H)-dione forms a three-dimensional hydrogen-bonded framework structure

M L G  Salido; M D G  Valero; J N  Low; C  Glidewell

doi:10.1107/S0108270103009302

6-Amino-3-methyl-5-nitrosopyrimidine-2,4(1H,3H)-dione forms a three-dimensional hydrogen-bonded framework structure

M L G Salido
, M D G Valero
, J N Low
, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Molecules of the title compound, C5H6N4O3, are linked into a single three-dimensional framework by a two-centre N-H...O hydrogen bond [H...O = 1.92 Angstrom, N...O = 2.785 (2) Angstrom and N - H...O = 168 degrees], a two-centre N - H...H hydrogen bond [H...N = 2.19 Angstrom, N...N = 3.017 (2) Angstrom and N - H...N = 157 degrees] and the intermolecular component of an effectively planar three- centre N - H...(O)(2) hydrogen bond [H...O = 2.03 and 2.31 Angstrom, N...O = 2.645 (2) and 2.957 (2) Angstrom, N-H...O = 126 and 130degrees, and O...H...O = 101 degrees].

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	59
DOIs	https://doi.org/10.1107/S0108270103009302
Publication status	Published - Jun 2003

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@article{956d932143b641cdb4ff42b72421271b,

title = "6-Amino-3-methyl-5-nitrosopyrimidine-2,4(1H,3H)-dione forms a three-dimensional hydrogen-bonded framework structure",

abstract = "Molecules of the title compound, C5H6N4O3, are linked into a single three-dimensional framework by a two-centre N-H...O hydrogen bond [H...O = 1.92 Angstrom, N...O = 2.785 (2) Angstrom and N - H...O = 168 degrees], a two-centre N - H...H hydrogen bond [H...N = 2.19 Angstrom, N...N = 3.017 (2) Angstrom and N - H...N = 157 degrees] and the intermolecular component of an effectively planar three- centre N - H...(O)(2) hydrogen bond [H...O = 2.03 and 2.31 Angstrom, N...O = 2.645 (2) and 2.957 (2) Angstrom, N-H...O = 126 and 130degrees, and O...H...O = 101 degrees].",

author = "Salido, \{M L G\} and Valero, \{M D G\} and Low, \{J N\} and C Glidewell",

year = "2003",

month = jun,

doi = "10.1107/S0108270103009302",

language = "English",

volume = "59",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - 6-Amino-3-methyl-5-nitrosopyrimidine-2,4(1H,3H)-dione forms a three-dimensional hydrogen-bonded framework structure

AU - Salido, M L G

AU - Valero, M D G

AU - Low, J N

AU - Glidewell, C

PY - 2003/6

Y1 - 2003/6

N2 - Molecules of the title compound, C5H6N4O3, are linked into a single three-dimensional framework by a two-centre N-H...O hydrogen bond [H...O = 1.92 Angstrom, N...O = 2.785 (2) Angstrom and N - H...O = 168 degrees], a two-centre N - H...H hydrogen bond [H...N = 2.19 Angstrom, N...N = 3.017 (2) Angstrom and N - H...N = 157 degrees] and the intermolecular component of an effectively planar three- centre N - H...(O)(2) hydrogen bond [H...O = 2.03 and 2.31 Angstrom, N...O = 2.645 (2) and 2.957 (2) Angstrom, N-H...O = 126 and 130degrees, and O...H...O = 101 degrees].

AB - Molecules of the title compound, C5H6N4O3, are linked into a single three-dimensional framework by a two-centre N-H...O hydrogen bond [H...O = 1.92 Angstrom, N...O = 2.785 (2) Angstrom and N - H...O = 168 degrees], a two-centre N - H...H hydrogen bond [H...N = 2.19 Angstrom, N...N = 3.017 (2) Angstrom and N - H...N = 157 degrees] and the intermolecular component of an effectively planar three- centre N - H...(O)(2) hydrogen bond [H...O = 2.03 and 2.31 Angstrom, N...O = 2.645 (2) and 2.957 (2) Angstrom, N-H...O = 126 and 130degrees, and O...H...O = 101 degrees].

U2 - 10.1107/S0108270103009302

DO - 10.1107/S0108270103009302

M3 - Article

SN - 1600-5759

SN - 0108-2701

VL - 59

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

6-Amino-3-methyl-5-nitrosopyrimidine-2,4(1H,3H)-dione forms a three-dimensional hydrogen-bonded framework structure

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