6-Amino-2-(3,4-dimethoxybenzylamino)-3-methyl-5-nitrosopyrimidin-4(3H)-one: hydrogen-bonded sheets form interdigitated bilayers

R  Abonia; C  Glidewell; J N  Low; M  Nogueras; J  Quiroga

doi:10.1107/S0108270103006231

6-Amino-2-(3,4-dimethoxybenzylamino)-3-methyl-5-nitrosopyrimidin-4(3H)-one: hydrogen-bonded sheets form interdigitated bilayers

R Abonia
, C Glidewell
, J N Low
, M Nogueras
, J Quiroga

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Molecules of the title compound, C14H17N5O4, exhibit a highly polarized molecular - electronic structure. The molecules are linked into sheets by two N - H...O hydrogen bonds [H...O = 2.03 and 2.02 Angstrom, N...O = 2.836 (2) and 2.887 (2) Angstrom, and N-H...O = 153 and 168degrees], augmented by a single C-H...O hydrogen bond [H...O = 2.47 Angstrom, C...O = 3.403 (2) Angstrom and C-H...O = 166degrees]. Pairs of sheets, related by inversion, form bilayers with interdigitated dimethoxybenzyl substituents, weakly linked by a further C-H...O interaction [H...O = 2.50 Angstrom, C...O = 3.350 (2) Angstrom and C - H...O = 146degrees].

Original language	English
Pages (from-to)	o237-o239
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	C59
DOIs	https://doi.org/10.1107/S0108270103006231
Publication status	Published - May 2003

Keywords

SUPRAMOLECULAR STRUCTURES
COORDINATION POLYMER
INTERPLAY

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@article{b97306ee2f434d03be8c97aefa53760c,

title = "6-Amino-2-(3,4-dimethoxybenzylamino)-3-methyl-5-nitrosopyrimidin-4(3H)-one: hydrogen-bonded sheets form interdigitated bilayers",

abstract = "Molecules of the title compound, C14H17N5O4, exhibit a highly polarized molecular - electronic structure. The molecules are linked into sheets by two N - H...O hydrogen bonds [H...O = 2.03 and 2.02 Angstrom, N...O = 2.836 (2) and 2.887 (2) Angstrom, and N-H...O = 153 and 168degrees], augmented by a single C-H...O hydrogen bond [H...O = 2.47 Angstrom, C...O = 3.403 (2) Angstrom and C-H...O = 166degrees]. Pairs of sheets, related by inversion, form bilayers with interdigitated dimethoxybenzyl substituents, weakly linked by a further C-H...O interaction [H...O = 2.50 Angstrom, C...O = 3.350 (2) Angstrom and C - H...O = 146degrees].",

keywords = "SUPRAMOLECULAR STRUCTURES, COORDINATION POLYMER, INTERPLAY",

author = "R Abonia and C Glidewell and Low, \{J N\} and M Nogueras and J Quiroga",

year = "2003",

month = may,

doi = "10.1107/S0108270103006231",

language = "English",

volume = "C59",

pages = "o237--o239",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - 6-Amino-2-(3,4-dimethoxybenzylamino)-3-methyl-5-nitrosopyrimidin-4(3H)-one: hydrogen-bonded sheets form interdigitated bilayers

AU - Abonia, R

AU - Glidewell, C

AU - Low, J N

AU - Nogueras, M

AU - Quiroga, J

PY - 2003/5

Y1 - 2003/5

N2 - Molecules of the title compound, C14H17N5O4, exhibit a highly polarized molecular - electronic structure. The molecules are linked into sheets by two N - H...O hydrogen bonds [H...O = 2.03 and 2.02 Angstrom, N...O = 2.836 (2) and 2.887 (2) Angstrom, and N-H...O = 153 and 168degrees], augmented by a single C-H...O hydrogen bond [H...O = 2.47 Angstrom, C...O = 3.403 (2) Angstrom and C-H...O = 166degrees]. Pairs of sheets, related by inversion, form bilayers with interdigitated dimethoxybenzyl substituents, weakly linked by a further C-H...O interaction [H...O = 2.50 Angstrom, C...O = 3.350 (2) Angstrom and C - H...O = 146degrees].

AB - Molecules of the title compound, C14H17N5O4, exhibit a highly polarized molecular - electronic structure. The molecules are linked into sheets by two N - H...O hydrogen bonds [H...O = 2.03 and 2.02 Angstrom, N...O = 2.836 (2) and 2.887 (2) Angstrom, and N-H...O = 153 and 168degrees], augmented by a single C-H...O hydrogen bond [H...O = 2.47 Angstrom, C...O = 3.403 (2) Angstrom and C-H...O = 166degrees]. Pairs of sheets, related by inversion, form bilayers with interdigitated dimethoxybenzyl substituents, weakly linked by a further C-H...O interaction [H...O = 2.50 Angstrom, C...O = 3.350 (2) Angstrom and C - H...O = 146degrees].

KW - SUPRAMOLECULAR STRUCTURES

KW - COORDINATION POLYMER

KW - INTERPLAY

U2 - 10.1107/S0108270103006231

DO - 10.1107/S0108270103006231

M3 - Article

SN - 0108-2701

VL - C59

SP - o237-o239

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

ER -

6-Amino-2-(3,4-dimethoxybenzylamino)-3-methyl-5-nitrosopyrimidin-4(3H)-one: hydrogen-bonded sheets form interdigitated bilayers

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