4-Fluorobenzyl (Z)-2-(2-oxoindolin-3-ylidene) hydrazine-1-carbodithioate

Mohd Abdul Fatah Abdul Manan*, David B. Cordes, Aidan P. McKay

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review


The title compound, C16H12FN3OS, a fluorinated dithiocarbazate imine derivative, was synthesized by the one-pot, multi-component condensation reaction of hydrazine hydrate, carbon disulfide, 4-fluorobenzyl chloride and isatin. The compound demonstrates near-planarity across much of the molecule in the solid state and a Z configuration for the azomethine C N bond. The Z form is further stabilized by the presence of an intramolecular N—H. . .O hydrogen bond. In the extended structure, molecules are linked into dimers by N—H. . .O hydrogen bonds and further connected into chains along either [210] or [100] by weak C—H. . .S and C—H. . .F hydrogen bonds, which further link into corrugated sheets and in combination form the overall three-dimensional network.

Original languageEnglish
Article numberx240235
Issue numberPt 3
Publication statusPublished - 1 Mar 2024


  • crystal structure
  • dithiocarbazate
  • fluorine
  • hydrogen bond
  • isatin
  • z configuration


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