4-Bromo-N,N'-bis­(4-methoxy­phen­yl)benzamidine

Amlan Kumar Pal; Garry S. Hanan

doi:10.1107/S1600536809040112

4-Bromo-N,N'-bis(4-methoxyphenyl)benzamidine

Amlan Kumar Pal, Garry S. Hanan

School of Chemistry

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title compound, C21H19BrN2O2, is an amidine containing electron-donating methoxy groups and a bulky Br atom on the benzene rings. The solid-state structure reveals a non-centrosymmetric molecule, with an E configuration around the C=N double bond. The C—N bonds show distinct amine [1.3689 (19) Å] and imine [1.285 (2) Å] characteristics. In the crystal, symmetry-related molecules are linked via a very weak N—H⋯N interaction, and C—H⋯O and C—H⋯π interactions.

Original language	English
Pages (from-to)	o2777
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	11
DOIs	https://doi.org/10.1107/S1600536809040112
Publication status	Published - 1 Nov 2009

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title = "4-Bromo-N,N'-bis(4-methoxyphenyl)benzamidine",

abstract = "The title compound, C21H19BrN2O2, is an amidine containing electron-donating methoxy groups and a bulky Br atom on the benzene rings. The solid-state structure reveals a non-centrosymmetric molecule, with an E configuration around the C=N double bond. The C—N bonds show distinct amine [1.3689 (19) {\AA}] and imine [1.285 (2) {\AA}] characteristics. In the crystal, symmetry-related molecules are linked via a very weak N—H⋯N interaction, and C—H⋯O and C—H⋯π interactions.",

author = "Pal, {Amlan Kumar} and Hanan, {Garry S.}",

year = "2009",

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publisher = "International Union of Crystallography",

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T1 - 4-Bromo-N,N'-bis(4-methoxyphenyl)benzamidine

AU - Pal, Amlan Kumar

AU - Hanan, Garry S.

PY - 2009/11/1

Y1 - 2009/11/1

N2 - The title compound, C21H19BrN2O2, is an amidine containing electron-donating methoxy groups and a bulky Br atom on the benzene rings. The solid-state structure reveals a non-centrosymmetric molecule, with an E configuration around the C=N double bond. The C—N bonds show distinct amine [1.3689 (19) Å] and imine [1.285 (2) Å] characteristics. In the crystal, symmetry-related molecules are linked via a very weak N—H⋯N interaction, and C—H⋯O and C—H⋯π interactions.

AB - The title compound, C21H19BrN2O2, is an amidine containing electron-donating methoxy groups and a bulky Br atom on the benzene rings. The solid-state structure reveals a non-centrosymmetric molecule, with an E configuration around the C=N double bond. The C—N bonds show distinct amine [1.3689 (19) Å] and imine [1.285 (2) Å] characteristics. In the crystal, symmetry-related molecules are linked via a very weak N—H⋯N interaction, and C—H⋯O and C—H⋯π interactions.

U2 - 10.1107/S1600536809040112

DO - 10.1107/S1600536809040112

M3 - Article

SN - 1600-5368

VL - 65

SP - o2777

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 11

ER -

4-Bromo-N,N'-bis­(4-methoxy­phen­yl)benzamidine

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4-Bromo-N,N'-bis(4-methoxyphenyl)benzamidine