4'-Bis(4-iodophenylaminomethyl)azoxybenzene: hydrogen-bonded sheets built from C-H...O and C-H..π(arene) hydrogen bonds

Christopher Glidewell; JN Low; JMS Skakle; JL Wardell

doi:10.1107/S0108270103005511

4'-Bis(4-iodophenylaminomethyl)azoxybenzene: hydrogen-bonded sheets built from C-H...O and C-H..π(arene) hydrogen bonds

Christopher Glidewell
, JN Low
, JMS Skakle
, JL Wardell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Borohydride reduction of N-(4-nitrobenzylidene)-4-iodoaniline has yielded the title compound, 1,2- bis[4-(4-iodophenylaminomethyl) phenyl] diazene 1-oxide, C26H22I2N4O. The molecules lie across centres of inversion in P2(1)/c, with the azoxy O atom disordered over two sites, each having an occupancy of 0.5. The molecules are linked into sheets by a combination of C-H...O and C-H...pi(arene) hydrogen bonds.

Original language	English
Pages (from-to)	o207-o209
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	C59
DOIs	https://doi.org/10.1107/S0108270103005511
Publication status	Published - Apr 2003

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title = "4'-Bis(4-iodophenylaminomethyl)azoxybenzene: hydrogen-bonded sheets built from C-H...O and C-H..π(arene) hydrogen bonds",

abstract = "Borohydride reduction of N-(4-nitrobenzylidene)-4-iodoaniline has yielded the title compound, 1,2- bis[4-(4-iodophenylaminomethyl) phenyl] diazene 1-oxide, C26H22I2N4O. The molecules lie across centres of inversion in P2(1)/c, with the azoxy O atom disordered over two sites, each having an occupancy of 0.5. The molecules are linked into sheets by a combination of C-H...O and C-H...pi(arene) hydrogen bonds.",

author = "Christopher Glidewell and JN Low and JMS Skakle and JL Wardell",

year = "2003",

month = apr,

doi = "10.1107/S0108270103005511",

language = "English",

volume = "C59",

pages = "o207--o209",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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publisher = "International Union of Crystallography",

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TY - JOUR

T1 - 4'-Bis(4-iodophenylaminomethyl)azoxybenzene: hydrogen-bonded sheets built from C-H...O and C-H..π(arene) hydrogen bonds

AU - Glidewell, Christopher

AU - Low, JN

AU - Skakle, JMS

AU - Wardell, JL

PY - 2003/4

Y1 - 2003/4

N2 - Borohydride reduction of N-(4-nitrobenzylidene)-4-iodoaniline has yielded the title compound, 1,2- bis[4-(4-iodophenylaminomethyl) phenyl] diazene 1-oxide, C26H22I2N4O. The molecules lie across centres of inversion in P2(1)/c, with the azoxy O atom disordered over two sites, each having an occupancy of 0.5. The molecules are linked into sheets by a combination of C-H...O and C-H...pi(arene) hydrogen bonds.

AB - Borohydride reduction of N-(4-nitrobenzylidene)-4-iodoaniline has yielded the title compound, 1,2- bis[4-(4-iodophenylaminomethyl) phenyl] diazene 1-oxide, C26H22I2N4O. The molecules lie across centres of inversion in P2(1)/c, with the azoxy O atom disordered over two sites, each having an occupancy of 0.5. The molecules are linked into sheets by a combination of C-H...O and C-H...pi(arene) hydrogen bonds.

U2 - 10.1107/S0108270103005511

DO - 10.1107/S0108270103005511

M3 - Article

SN - 0108-2701

VL - C59

SP - o207-o209

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

ER -

4'-Bis(4-iodophenylaminomethyl)azoxybenzene: hydrogen-bonded sheets built from C-H...O and C-H..π(arene) hydrogen bonds

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