4-Amino-6-benzyloxy-2-(methylsulfanyl)-5-nitrosopyrimidine: hydrogen-bonded dimers linked into pi-stacked chains

J N  Low; A  Quesada; A  Marchal; M  Nogueras; A  Sanchez; C  Glidewell

doi:10.1107/S0108270102005735

4-Amino-6-benzyloxy-2-(methylsulfanyl)-5-nitrosopyrimidine: hydrogen-bonded dimers linked into pi-stacked chains

J N Low, A Quesada, A Marchal, M Nogueras, A Sanchez, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, C12H12N4O2S, crystallizes with Z' = 2 in space group P2(1)/c. The intramolecular dimensions are consistent with a highly polarized electronic structure. Each of the independent molecules forms a centrosymmetric dimer linked by paired N-H...N hydrogen bonds, and these dimers are linked into a single type of chain by aromatic pi-pi-stacking interactions.

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	58
DOIs	https://doi.org/10.1107/S0108270102005735
Publication status	Published - May 2002

Keywords

SUPRAMOLECULAR STRUCTURES
INTERPLAY
DERIVATIVES

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10.1107/S0108270102005735

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title = "4-Amino-6-benzyloxy-2-(methylsulfanyl)-5-nitrosopyrimidine: hydrogen-bonded dimers linked into pi-stacked chains",

abstract = "The title compound, C12H12N4O2S, crystallizes with Z' = 2 in space group P2(1)/c. The intramolecular dimensions are consistent with a highly polarized electronic structure. Each of the independent molecules forms a centrosymmetric dimer linked by paired N-H...N hydrogen bonds, and these dimers are linked into a single type of chain by aromatic pi-pi-stacking interactions.",

keywords = "SUPRAMOLECULAR STRUCTURES, INTERPLAY, DERIVATIVES",

author = "Low, {J N} and A Quesada and A Marchal and M Nogueras and A Sanchez and C Glidewell",

year = "2002",

month = may,

doi = "10.1107/S0108270102005735",

language = "English",

volume = "58",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

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T1 - 4-Amino-6-benzyloxy-2-(methylsulfanyl)-5-nitrosopyrimidine: hydrogen-bonded dimers linked into pi-stacked chains

AU - Low, J N

AU - Quesada, A

AU - Marchal, A

AU - Nogueras, M

AU - Sanchez, A

AU - Glidewell, C

PY - 2002/5

Y1 - 2002/5

N2 - The title compound, C12H12N4O2S, crystallizes with Z' = 2 in space group P2(1)/c. The intramolecular dimensions are consistent with a highly polarized electronic structure. Each of the independent molecules forms a centrosymmetric dimer linked by paired N-H...N hydrogen bonds, and these dimers are linked into a single type of chain by aromatic pi-pi-stacking interactions.

AB - The title compound, C12H12N4O2S, crystallizes with Z' = 2 in space group P2(1)/c. The intramolecular dimensions are consistent with a highly polarized electronic structure. Each of the independent molecules forms a centrosymmetric dimer linked by paired N-H...N hydrogen bonds, and these dimers are linked into a single type of chain by aromatic pi-pi-stacking interactions.

KW - SUPRAMOLECULAR STRUCTURES

KW - INTERPLAY

KW - DERIVATIVES

U2 - 10.1107/S0108270102005735

DO - 10.1107/S0108270102005735

M3 - Article

SN - 1600-5759

VL - 58

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

4-Amino-6-benzyloxy-2-(methylsulfanyl)-5-nitrosopyrimidine: hydrogen-bonded dimers linked into pi-stacked chains

Abstract

Keywords

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