4-Amino-2,6-dimethoxypyrimidine: hydrogen-bonded sheets R-2(2)(8) and R-6(6)(28) rings, reinforced by an aromatic pi-pi-stacking interaction

C  Glidewell; J N  Low; M  Melguizo; A  Quesada

doi:10.1107/S010827010300547X

4-Amino-2,6-dimethoxypyrimidine: hydrogen-bonded sheets R-2(2)(8) and R-6(6)(28) rings, reinforced by an aromatic pi-pi-stacking interaction

C Glidewell, J N Low, M Melguizo, A Quesada

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Molecules of the title compound, C6H9N3O2, are linked by an N-H...O hydrogen bond [H...O = 2.29 Angstrom, N...O = 3.169 (2) Angstrom and N-H...O = 173degrees] and an N-H...N hydrogen bond [H...N = 2.12 Angstrom, N...N = 2.999 (2) Angstrom and N-H...N = 175 degrees] into sheets containing centrosymmetric R-2(2)( 8) and R-6(6)(28) rings; the sheets are reinforced by a single aromatic pi-pi-stacking interaction.

Original language	English
Number of pages	3
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	59
DOIs	https://doi.org/10.1107/S010827010300547X
Publication status	Published - Apr 2003

Keywords

SUPRAMOLECULAR STRUCTURES
INTERPLAY

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title = "4-Amino-2,6-dimethoxypyrimidine: hydrogen-bonded sheets R-2(2)(8) and R-6(6)(28) rings, reinforced by an aromatic pi-pi-stacking interaction",

abstract = "Molecules of the title compound, C6H9N3O2, are linked by an N-H...O hydrogen bond [H...O = 2.29 Angstrom, N...O = 3.169 (2) Angstrom and N-H...O = 173degrees] and an N-H...N hydrogen bond [H...N = 2.12 Angstrom, N...N = 2.999 (2) Angstrom and N-H...N = 175 degrees] into sheets containing centrosymmetric R-2(2)( 8) and R-6(6)(28) rings; the sheets are reinforced by a single aromatic pi-pi-stacking interaction.",

keywords = "SUPRAMOLECULAR STRUCTURES, INTERPLAY",

author = "C Glidewell and Low, {J N} and M Melguizo and A Quesada",

year = "2003",

month = apr,

doi = "10.1107/S010827010300547X",

language = "English",

volume = "59",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - 4-Amino-2,6-dimethoxypyrimidine: hydrogen-bonded sheets R-2(2)(8) and R-6(6)(28) rings, reinforced by an aromatic pi-pi-stacking interaction

AU - Glidewell, C

AU - Low, J N

AU - Melguizo, M

AU - Quesada, A

PY - 2003/4

Y1 - 2003/4

N2 - Molecules of the title compound, C6H9N3O2, are linked by an N-H...O hydrogen bond [H...O = 2.29 Angstrom, N...O = 3.169 (2) Angstrom and N-H...O = 173degrees] and an N-H...N hydrogen bond [H...N = 2.12 Angstrom, N...N = 2.999 (2) Angstrom and N-H...N = 175 degrees] into sheets containing centrosymmetric R-2(2)( 8) and R-6(6)(28) rings; the sheets are reinforced by a single aromatic pi-pi-stacking interaction.

AB - Molecules of the title compound, C6H9N3O2, are linked by an N-H...O hydrogen bond [H...O = 2.29 Angstrom, N...O = 3.169 (2) Angstrom and N-H...O = 173degrees] and an N-H...N hydrogen bond [H...N = 2.12 Angstrom, N...N = 2.999 (2) Angstrom and N-H...N = 175 degrees] into sheets containing centrosymmetric R-2(2)( 8) and R-6(6)(28) rings; the sheets are reinforced by a single aromatic pi-pi-stacking interaction.

KW - SUPRAMOLECULAR STRUCTURES

KW - INTERPLAY

U2 - 10.1107/S010827010300547X

DO - 10.1107/S010827010300547X

M3 - Article

SN - 1600-5759

VL - 59

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

4-Amino-2,6-dimethoxypyrimidine: hydrogen-bonded sheets R-2(2)(8) and R-6(6)(28) rings, reinforced by an aromatic pi-pi-stacking interaction

Abstract

Keywords

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