4-(Allylamino)-2-amino-6-benzyloxy-5-nitrosopyrimidine from synchrotron data at 150 K: double chains built from N-H...N, N-H...O, N-H...p(arene) and aromatic m stacking interactions

J Maclean; JN Low; A Quesada; M Melguizo; M Nogueras; Christopher Glidewell

doi:10.1107/S0108270102010387

4-(Allylamino)-2-amino-6-benzyloxy-5-nitrosopyrimidine from synchrotron data at 150 K: double chains built from N-H...N, N-H...O, N-H...p(arene) and aromatic m stacking interactions

J Maclean, JN Low, A Quesada, M Melguizo, M Nogueras, Christopher Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, C14H15N5O2, the intramolecular dimensions are consistent with a highly polarized electronic structure. The molecules are linked into chains by a combination of N-H...N, N-H...O and N-H...pi(arene) hydrogen bonds, and the chains are linked in pairs by aromatic pi-pi-stacking interactions.

Original language	English
Pages (from-to)	o442-o444
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	C58
DOIs	https://doi.org/10.1107/S0108270102010387
Publication status	Published - Jul 2002

Keywords

CRYSTALLOGRAPHY
DERIVATIVES
CRYSTALS

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10.1107/S0108270102010387

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Maclean, J., Low, JN., Quesada, A., Melguizo, M., Nogueras, M., & Glidewell, C. (2002). 4-(Allylamino)-2-amino-6-benzyloxy-5-nitrosopyrimidine from synchrotron data at 150 K: double chains built from N-H...N, N-H...O, N-H...p(arene) and aromatic m stacking interactions. Acta Crystallographica Section C: Crystal Structure Communications, C58, o442-o444. https://doi.org/10.1107/S0108270102010387

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title = "4-(Allylamino)-2-amino-6-benzyloxy-5-nitrosopyrimidine from synchrotron data at 150 K: double chains built from N-H...N, N-H...O, N-H...p(arene) and aromatic m stacking interactions",

abstract = "In the title compound, C14H15N5O2, the intramolecular dimensions are consistent with a highly polarized electronic structure. The molecules are linked into chains by a combination of N-H...N, N-H...O and N-H...pi(arene) hydrogen bonds, and the chains are linked in pairs by aromatic pi-pi-stacking interactions.",

keywords = "CRYSTALLOGRAPHY, DERIVATIVES, CRYSTALS",

author = "J Maclean and JN Low and A Quesada and M Melguizo and M Nogueras and Christopher Glidewell",

year = "2002",

month = jul,

doi = "10.1107/S0108270102010387",

language = "English",

volume = "C58",

pages = "o442--o444",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

}

Maclean, J, Low, JN, Quesada, A, Melguizo, M, Nogueras, M & Glidewell, C 2002, '4-(Allylamino)-2-amino-6-benzyloxy-5-nitrosopyrimidine from synchrotron data at 150 K: double chains built from N-H...N, N-H...O, N-H...p(arene) and aromatic m stacking interactions', Acta Crystallographica Section C: Crystal Structure Communications, vol. C58, pp. o442-o444. https://doi.org/10.1107/S0108270102010387

4-(Allylamino)-2-amino-6-benzyloxy-5-nitrosopyrimidine from synchrotron data at 150 K: double chains built from N-H...N, N-H...O, N-H...p(arene) and aromatic m stacking interactions. / Maclean, J; Low, JN; Quesada, A et al.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. C58, 07.2002, p. o442-o444.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - 4-(Allylamino)-2-amino-6-benzyloxy-5-nitrosopyrimidine from synchrotron data at 150 K: double chains built from N-H...N, N-H...O, N-H...p(arene) and aromatic m stacking interactions

AU - Maclean, J

AU - Low, JN

AU - Quesada, A

AU - Melguizo, M

AU - Nogueras, M

AU - Glidewell, Christopher

PY - 2002/7

Y1 - 2002/7

N2 - In the title compound, C14H15N5O2, the intramolecular dimensions are consistent with a highly polarized electronic structure. The molecules are linked into chains by a combination of N-H...N, N-H...O and N-H...pi(arene) hydrogen bonds, and the chains are linked in pairs by aromatic pi-pi-stacking interactions.

AB - In the title compound, C14H15N5O2, the intramolecular dimensions are consistent with a highly polarized electronic structure. The molecules are linked into chains by a combination of N-H...N, N-H...O and N-H...pi(arene) hydrogen bonds, and the chains are linked in pairs by aromatic pi-pi-stacking interactions.

KW - CRYSTALLOGRAPHY

KW - DERIVATIVES

KW - CRYSTALS

U2 - 10.1107/S0108270102010387

DO - 10.1107/S0108270102010387

M3 - Article

SN - 0108-2701

VL - C58

SP - o442-o444

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

ER -

Maclean J, Low JN, Quesada A, Melguizo M, Nogueras M, Glidewell C. 4-(Allylamino)-2-amino-6-benzyloxy-5-nitrosopyrimidine from synchrotron data at 150 K: double chains built from N-H...N, N-H...O, N-H...p(arene) and aromatic m stacking interactions. Acta Crystallographica Section C: Crystal Structure Communications. 2002 Jul;C58:o442-o444. doi: 10.1107/S0108270102010387

4-(Allylamino)-2-amino-6-benzyloxy-5-nitrosopyrimidine from synchrotron data at 150 K: double chains built from N-H...N, N-H...O, N-H...p(arene) and aromatic m stacking interactions

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Keywords

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