2,8-Dibromo-6H,12H-6,12-epoxydibenzo[b,f][1,5]dioxocine

R Alan Aitken; David Bradford Cordes; An Jie Ler; Aidan McKay

doi:10.3390/M1729

2,8-Dibromo-6H,12H-6,12-epoxydibenzo[b,f][1,5]dioxocine

R Alan Aitken^*, David Bradford Cordes, An Jie Ler, Aidan McKay

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The title dibromodisalicylaldehyde, obtained as a by-product in the m-chloroperoxybenzoic acid oxidation of 5-bromo-2-(methoxymethoxy)benzaldehyde, has been characterised by IR and NMR spectroscopy and X-ray diffraction. The structure features two independent molecules with a π–π stacking interaction between them.

Original language	English
Article number	M1729
Number of pages	5
Journal	Molbank
Volume	2023
Issue number	3
DOIs	https://doi.org/10.3390/M1729
Publication status	Published - 19 Sept 2023

Keywords

X-ray structure
Disalicylaldehyde
Trioxabicyclo[3.3.1]nonadiene

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10.3390/M1729Licence: CC BY

Aitken-2023-Molbank-2023-M1729-CCBY
Copyright © 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Final published version, 2.32 MBLicence: CC BY

Cite this

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title = "2,8-Dibromo-6H,12H-6,12-epoxydibenzo[b,f][1,5]dioxocine",

abstract = "The title dibromodisalicylaldehyde, obtained as a by-product in the m-chloroperoxybenzoic acid oxidation of 5-bromo-2-(methoxymethoxy)benzaldehyde, has been characterised by IR and NMR spectroscopy and X-ray diffraction. The structure features two independent molecules with a π–π stacking interaction between them.",

keywords = "X-ray structure, Disalicylaldehyde, Trioxabicyclo[3.3.1]nonadiene",

author = "Aitken, {R Alan} and Cordes, {David Bradford} and Ler, {An Jie} and Aidan McKay",

year = "2023",

month = sep,

day = "19",

doi = "10.3390/M1729",

language = "English",

volume = "2023",

journal = "Molbank",

issn = "1422-8599",

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number = "3",

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TY - JOUR

T1 - 2,8-Dibromo-6H,12H-6,12-epoxydibenzo[b,f][1,5]dioxocine

AU - Aitken, R Alan

AU - Cordes, David Bradford

AU - Ler, An Jie

AU - McKay, Aidan

PY - 2023/9/19

Y1 - 2023/9/19

N2 - The title dibromodisalicylaldehyde, obtained as a by-product in the m-chloroperoxybenzoic acid oxidation of 5-bromo-2-(methoxymethoxy)benzaldehyde, has been characterised by IR and NMR spectroscopy and X-ray diffraction. The structure features two independent molecules with a π–π stacking interaction between them.

AB - The title dibromodisalicylaldehyde, obtained as a by-product in the m-chloroperoxybenzoic acid oxidation of 5-bromo-2-(methoxymethoxy)benzaldehyde, has been characterised by IR and NMR spectroscopy and X-ray diffraction. The structure features two independent molecules with a π–π stacking interaction between them.

KW - X-ray structure

KW - Disalicylaldehyde

KW - Trioxabicyclo[3.3.1]nonadiene

UR - https://www.mdpi.com/journal/molbank/special_issues/side_reaction_II

U2 - 10.3390/M1729

DO - 10.3390/M1729

M3 - Article

SN - 1422-8599

VL - 2023

JO - Molbank

JF - Molbank

IS - 3

M1 - M1729

ER -

2,8-Dibromo-6H,12H-6,12-epoxydibenzo[b,f][1,5]dioxocine

Abstract

Keywords

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CCDC 2290326: Experimental Crystal Structure Determination

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2,8-Dibromo-6H,12H-6,12-epoxydibenzo[b,f][1,5]dioxocine

Abstract

Keywords

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Other files and links

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Datasets

CCDC 2290326: Experimental Crystal Structure Determination

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