2,4-difluorobenzaldehyde benzoylhydrazone and 2,4-dichlorobenzaldehyde benzoylhydrazone are isostructural at 120 K with Z '=2: complex sheets built from N-H center dot center dot center dot O, C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds

S M S V  Wardell; M D  Ferreira; M V N  de Souza; J L  Wardell; J N  Low; C  Glidewell

doi:10.1107/S0108270106001995

2,4-difluorobenzaldehyde benzoylhydrazone and 2,4-dichlorobenzaldehyde benzoylhydrazone are isostructural at 120 K with Z '=2: complex sheets built from N-H center dot center dot center dot O, C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds

S M S V Wardell
, M D Ferreira
, M V N de Souza
, J L Wardell
, J N Low
, C Glidewell

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

At 120 K, 2,4-diflorobenzaldehydebenzoylhydrazone, C14H10F2N2O, (I), and 2,4-dichlorobenzaldehyde benzoylhydrazone, C14H10Cl2N2O, (II), are isomorphous and isostructural in P2(1)/n with Z' = 2. In each structure, eight independent hydrogen bonds, viz. two of N-H center dot center dot center dot O type, five of C-H center dot center dot center dot O type and one of C-H center dot center dot center dot pi(arene) type, link the molecules into complex sheets, within which two independent one-dimensional substructures can be identified.

Original language	English
Number of pages	4
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	62
DOIs	https://doi.org/10.1107/S0108270106001995
Publication status	Published - Mar 2006

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Wardell, S. M. S. V., Ferreira, M. D., de Souza, M. V. N., Wardell, J. L., Low, J. N., & Glidewell, C. (2006). 2,4-difluorobenzaldehyde benzoylhydrazone and 2,4-dichlorobenzaldehyde benzoylhydrazone are isostructural at 120 K with Z '=2: complex sheets built from N-H center dot center dot center dot O, C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds. Acta Crystallographica Section C-Crystal Structure Communications, 62. https://doi.org/10.1107/S0108270106001995

Wardell, S M S V ; Ferreira, M D ; de Souza, M V N et al. / 2,4-difluorobenzaldehyde benzoylhydrazone and 2,4-dichlorobenzaldehyde benzoylhydrazone are isostructural at 120 K with Z '=2: complex sheets built from N-H center dot center dot center dot O, C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds. In: Acta Crystallographica Section C-Crystal Structure Communications. 2006 ; Vol. 62.

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title = "2,4-difluorobenzaldehyde benzoylhydrazone and 2,4-dichlorobenzaldehyde benzoylhydrazone are isostructural at 120 K with Z '=2: complex sheets built from N-H center dot center dot center dot O, C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds",

abstract = "At 120 K, 2,4-diflorobenzaldehydebenzoylhydrazone, C14H10F2N2O, (I), and 2,4-dichlorobenzaldehyde benzoylhydrazone, C14H10Cl2N2O, (II), are isomorphous and isostructural in P2(1)/n with Z' = 2. In each structure, eight independent hydrogen bonds, viz. two of N-H center dot center dot center dot O type, five of C-H center dot center dot center dot O type and one of C-H center dot center dot center dot pi(arene) type, link the molecules into complex sheets, within which two independent one-dimensional substructures can be identified.",

author = "Wardell, \{S M S V\} and Ferreira, \{M D\} and \{de Souza\}, \{M V N\} and Wardell, \{J L\} and Low, \{J N\} and C Glidewell",

year = "2006",

month = mar,

doi = "10.1107/S0108270106001995",

language = "English",

volume = "62",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

}

Wardell, SMSV, Ferreira, MD, de Souza, MVN, Wardell, JL, Low, JN & Glidewell, C 2006, '2,4-difluorobenzaldehyde benzoylhydrazone and 2,4-dichlorobenzaldehyde benzoylhydrazone are isostructural at 120 K with Z '=2: complex sheets built from N-H center dot center dot center dot O, C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds', Acta Crystallographica Section C-Crystal Structure Communications, vol. 62. https://doi.org/10.1107/S0108270106001995

2,4-difluorobenzaldehyde benzoylhydrazone and 2,4-dichlorobenzaldehyde benzoylhydrazone are isostructural at 120 K with Z '=2: complex sheets built from N-H center dot center dot center dot O, C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds. / Wardell, S M S V ; Ferreira, M D ; de Souza, M V N et al.
In: Acta Crystallographica Section C-Crystal Structure Communications, Vol. 62, 03.2006.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - 2,4-difluorobenzaldehyde benzoylhydrazone and 2,4-dichlorobenzaldehyde benzoylhydrazone are isostructural at 120 K with Z '=2: complex sheets built from N-H center dot center dot center dot O, C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds

AU - Wardell, S M S V

AU - Ferreira, M D

AU - de Souza, M V N

AU - Wardell, J L

AU - Low, J N

AU - Glidewell, C

PY - 2006/3

Y1 - 2006/3

N2 - At 120 K, 2,4-diflorobenzaldehydebenzoylhydrazone, C14H10F2N2O, (I), and 2,4-dichlorobenzaldehyde benzoylhydrazone, C14H10Cl2N2O, (II), are isomorphous and isostructural in P2(1)/n with Z' = 2. In each structure, eight independent hydrogen bonds, viz. two of N-H center dot center dot center dot O type, five of C-H center dot center dot center dot O type and one of C-H center dot center dot center dot pi(arene) type, link the molecules into complex sheets, within which two independent one-dimensional substructures can be identified.

AB - At 120 K, 2,4-diflorobenzaldehydebenzoylhydrazone, C14H10F2N2O, (I), and 2,4-dichlorobenzaldehyde benzoylhydrazone, C14H10Cl2N2O, (II), are isomorphous and isostructural in P2(1)/n with Z' = 2. In each structure, eight independent hydrogen bonds, viz. two of N-H center dot center dot center dot O type, five of C-H center dot center dot center dot O type and one of C-H center dot center dot center dot pi(arene) type, link the molecules into complex sheets, within which two independent one-dimensional substructures can be identified.

U2 - 10.1107/S0108270106001995

DO - 10.1107/S0108270106001995

M3 - Article

SN - 1600-5759

SN - 0108-2701

VL - 62

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

Wardell SMSV, Ferreira MD, de Souza MVN, Wardell JL, Low JN, Glidewell C. 2,4-difluorobenzaldehyde benzoylhydrazone and 2,4-dichlorobenzaldehyde benzoylhydrazone are isostructural at 120 K with Z '=2: complex sheets built from N-H center dot center dot center dot O, C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds. Acta Crystallographica Section C-Crystal Structure Communications. 2006 Mar;62. doi: 10.1107/S0108270106001995