2,4-Diferrocenyl-1,3-dithiadiphosphetane 2,4-disulfide; Structure and reactions with catechols and [PtCl2(PR(3))(2)] (R=Et or Bu(II))

M R S J  Foreman; A M Z  Slawin; J D  Woollins

doi:10.1039/dt9960003653

2,4-Diferrocenyl-1,3-dithiadiphosphetane 2,4-disulfide; Structure and reactions with catechols and [PtCl2(PR(3))(2)] (R=Et or Bu(II))

M R S J Foreman, A M Z Slawin, J D Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of ferrocene (or 1,1'-dimethylferrocene) with P4S10 yielded R'P(S)S2P(S)R' (R' = ferrocenyl) (or the analogous dimethylferrocene species). This compound reacted with catechols to form R'P(S)O2C2 ring systems and with [PtCl2(PR(3))(2)] (R = Et or Bu(II)) to give [R'PS3Pt(PR(3))(2)]. The new compounds have been characterised spectroscopically with illustrative examples having been fully studied by X-ray crystallography.

Original language	English
Pages (from-to)	3653-3657
Number of pages	5
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	18
DOIs	https://doi.org/10.1039/dt9960003653
Publication status	Published - 21 Sept 1996

Keywords

X-RAY STRUCTURE
LAWESSONS REAGENT

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title = "2,4-Diferrocenyl-1,3-dithiadiphosphetane 2,4-disulfide; Structure and reactions with catechols and [PtCl2(PR(3))(2)] (R=Et or Bu(II))",

abstract = "Reaction of ferrocene (or 1,1'-dimethylferrocene) with P4S10 yielded R'P(S)S2P(S)R' (R' = ferrocenyl) (or the analogous dimethylferrocene species). This compound reacted with catechols to form R'P(S)O2C2 ring systems and with [PtCl2(PR(3))(2)] (R = Et or Bu(II)) to give [R'PS3Pt(PR(3))(2)]. The new compounds have been characterised spectroscopically with illustrative examples having been fully studied by X-ray crystallography.",

keywords = "X-RAY STRUCTURE, LAWESSONS REAGENT",

author = "Foreman, {M R S J} and Slawin, {A M Z} and Woollins, {J D}",

year = "1996",

month = sep,

day = "21",

doi = "10.1039/dt9960003653",

language = "English",

pages = "3653--3657",

journal = "Journal of the Chemical Society, Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - 2,4-Diferrocenyl-1,3-dithiadiphosphetane 2,4-disulfide; Structure and reactions with catechols and [PtCl2(PR(3))(2)] (R=Et or Bu(II))

AU - Foreman, M R S J

AU - Slawin, A M Z

AU - Woollins, J D

PY - 1996/9/21

Y1 - 1996/9/21

N2 - Reaction of ferrocene (or 1,1'-dimethylferrocene) with P4S10 yielded R'P(S)S2P(S)R' (R' = ferrocenyl) (or the analogous dimethylferrocene species). This compound reacted with catechols to form R'P(S)O2C2 ring systems and with [PtCl2(PR(3))(2)] (R = Et or Bu(II)) to give [R'PS3Pt(PR(3))(2)]. The new compounds have been characterised spectroscopically with illustrative examples having been fully studied by X-ray crystallography.

AB - Reaction of ferrocene (or 1,1'-dimethylferrocene) with P4S10 yielded R'P(S)S2P(S)R' (R' = ferrocenyl) (or the analogous dimethylferrocene species). This compound reacted with catechols to form R'P(S)O2C2 ring systems and with [PtCl2(PR(3))(2)] (R = Et or Bu(II)) to give [R'PS3Pt(PR(3))(2)]. The new compounds have been characterised spectroscopically with illustrative examples having been fully studied by X-ray crystallography.

KW - X-RAY STRUCTURE

KW - LAWESSONS REAGENT

U2 - 10.1039/dt9960003653

DO - 10.1039/dt9960003653

M3 - Article

SN - 0300-9246

SP - 3653

EP - 3657

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 18

ER -

2,4-Diferrocenyl-1,3-dithiadiphosphetane 2,4-disulfide; Structure and reactions with catechols and [PtCl2(PR(3))(2)] (R=Et or Bu(II))

Abstract

Keywords

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