1ST SYNTHESIS OF SULFONYL SUBSTITUTED TRICARBONYL[ETA(6)-ARENE]CHROMIUM(0) COMPLEXES

C F  MARCOS; S  PERRIO; A M Z  SLAWIN; S E  THOMAS; D J  WILLIAMS

1ST SYNTHESIS OF SULFONYL SUBSTITUTED TRICARBONYL[ETA(6)-ARENE]CHROMIUM(0) COMPLEXES

C F MARCOS
, S PERRIO
, A M Z SLAWIN
, S E THOMAS
, D J WILLIAMS

Research output: Contribution to journal › Article › peer-review

Abstract

Sulfonyl substituted tricarbonyl(eta6-arene)chromium(0) complexes may be prepared by thermolysis of sulfonyl substituted arenes with Cr(CO)6/BuOAc and/or selective oxidation of sulfenyl substituted tricarbonyl(eta6-arene)chromium(0) complexes with cumene hydroperoxide in the presence of a Ti(OPri)4/diethyl tartrate/H2O catalyst.

Original language	English
Pages (from-to)	753-754
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	6
Publication status	Published - 21 Mar 1994

Keywords

DERIVATIVES
OXIDATIONS
ARENES

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@article{10e959426f444ac2a6435c37e508af94,

title = "1ST SYNTHESIS OF SULFONYL SUBSTITUTED TRICARBONYL[ETA(6)-ARENE]CHROMIUM(0) COMPLEXES",

abstract = "Sulfonyl substituted tricarbonyl(eta6-arene)chromium(0) complexes may be prepared by thermolysis of sulfonyl substituted arenes with Cr(CO)6/BuOAc and/or selective oxidation of sulfenyl substituted tricarbonyl(eta6-arene)chromium(0) complexes with cumene hydroperoxide in the presence of a Ti(OPri)4/diethyl tartrate/H2O catalyst.",

keywords = "DERIVATIVES, OXIDATIONS, ARENES",

author = "MARCOS, \{C F\} and S PERRIO and SLAWIN, \{A M Z\} and THOMAS, \{S E\} and WILLIAMS, \{D J\}",

year = "1994",

month = mar,

day = "21",

language = "English",

pages = "753--754",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "6",

}

TY - JOUR

T1 - 1ST SYNTHESIS OF SULFONYL SUBSTITUTED TRICARBONYL[ETA(6)-ARENE]CHROMIUM(0) COMPLEXES

AU - MARCOS, C F

AU - PERRIO, S

AU - SLAWIN, A M Z

AU - THOMAS, S E

AU - WILLIAMS, D J

PY - 1994/3/21

Y1 - 1994/3/21

N2 - Sulfonyl substituted tricarbonyl(eta6-arene)chromium(0) complexes may be prepared by thermolysis of sulfonyl substituted arenes with Cr(CO)6/BuOAc and/or selective oxidation of sulfenyl substituted tricarbonyl(eta6-arene)chromium(0) complexes with cumene hydroperoxide in the presence of a Ti(OPri)4/diethyl tartrate/H2O catalyst.

AB - Sulfonyl substituted tricarbonyl(eta6-arene)chromium(0) complexes may be prepared by thermolysis of sulfonyl substituted arenes with Cr(CO)6/BuOAc and/or selective oxidation of sulfenyl substituted tricarbonyl(eta6-arene)chromium(0) complexes with cumene hydroperoxide in the presence of a Ti(OPri)4/diethyl tartrate/H2O catalyst.

KW - DERIVATIVES

KW - OXIDATIONS

KW - ARENES

M3 - Article

SN - 0022-4936

SP - 753

EP - 754

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 6

ER -

1ST SYNTHESIS OF SULFONYL SUBSTITUTED TRICARBONYL[ETA(6)-ARENE]CHROMIUM(0) COMPLEXES

Abstract

Keywords

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