(1RS,2RS)-N,N '-Bis(4-nitrophenylmethylene)cyclohexane-1,2-diamine: complex sheets built from C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds

C  Glidewell; J N  Low; J M S  Skakle; J L  Wardell

doi:10.1107/S0108270105024443

(1RS,2RS)-N,N '-Bis(4-nitrophenylmethylene)cyclohexane-1,2-diamine: complex sheets built from C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds

C Glidewell, J N Low, J M S Skakle, J L Wardell

School of Chemistry

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Abstract

The racemic title compound, C20H20N4O4, crystallizes with Z' = 2 in the space group P2(1)/c. Each independent molecule exhibits approximate twofold rotation symmetry, but conformational differences between the molecules preclude any higher symmetry. The molecules are linked into complex sheets by a combination of four C-H center dot center dot center dot O hydrogen bonds and two C-H center dot center dot center dot pi(arene) hydrogen bonds.

Original language	English
Number of pages	4
Journal	Acta Crystallographica Section C-Crystal Structure Communications
Volume	61
DOIs	https://doi.org/10.1107/S0108270105024443
Publication status	Published - Sept 2005

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Glidewell, C., Low, J. N., Skakle, J. M. S., & Wardell, J. L. (2005). (1RS,2RS)-N,N '-Bis(4-nitrophenylmethylene)cyclohexane-1,2-diamine: complex sheets built from C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds. Acta Crystallographica Section C-Crystal Structure Communications, 61. https://doi.org/10.1107/S0108270105024443

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title = "(1RS,2RS)-N,N '-Bis(4-nitrophenylmethylene)cyclohexane-1,2-diamine: complex sheets built from C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds",

abstract = "The racemic title compound, C20H20N4O4, crystallizes with Z' = 2 in the space group P2(1)/c. Each independent molecule exhibits approximate twofold rotation symmetry, but conformational differences between the molecules preclude any higher symmetry. The molecules are linked into complex sheets by a combination of four C-H center dot center dot center dot O hydrogen bonds and two C-H center dot center dot center dot pi(arene) hydrogen bonds.",

author = "C Glidewell and Low, {J N} and Skakle, {J M S} and Wardell, {J L}",

year = "2005",

month = sep,

doi = "10.1107/S0108270105024443",

language = "English",

volume = "61",

journal = "Acta Crystallographica Section C-Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

}

Glidewell, C, Low, JN, Skakle, JMS & Wardell, JL 2005, '(1RS,2RS)-N,N '-Bis(4-nitrophenylmethylene)cyclohexane-1,2-diamine: complex sheets built from C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds', Acta Crystallographica Section C-Crystal Structure Communications, vol. 61. https://doi.org/10.1107/S0108270105024443

(1RS,2RS)-N,N '-Bis(4-nitrophenylmethylene)cyclohexane-1,2-diamine: complex sheets built from C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds. / Glidewell, C ; Low, J N ; Skakle, J M S et al.
In: Acta Crystallographica Section C-Crystal Structure Communications, Vol. 61, 09.2005.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - (1RS,2RS)-N,N '-Bis(4-nitrophenylmethylene)cyclohexane-1,2-diamine: complex sheets built from C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds

AU - Glidewell, C

AU - Low, J N

AU - Skakle, J M S

AU - Wardell, J L

PY - 2005/9

Y1 - 2005/9

N2 - The racemic title compound, C20H20N4O4, crystallizes with Z' = 2 in the space group P2(1)/c. Each independent molecule exhibits approximate twofold rotation symmetry, but conformational differences between the molecules preclude any higher symmetry. The molecules are linked into complex sheets by a combination of four C-H center dot center dot center dot O hydrogen bonds and two C-H center dot center dot center dot pi(arene) hydrogen bonds.

AB - The racemic title compound, C20H20N4O4, crystallizes with Z' = 2 in the space group P2(1)/c. Each independent molecule exhibits approximate twofold rotation symmetry, but conformational differences between the molecules preclude any higher symmetry. The molecules are linked into complex sheets by a combination of four C-H center dot center dot center dot O hydrogen bonds and two C-H center dot center dot center dot pi(arene) hydrogen bonds.

U2 - 10.1107/S0108270105024443

DO - 10.1107/S0108270105024443

M3 - Article

SN - 1600-5759

VL - 61

JO - Acta Crystallographica Section C-Crystal Structure Communications

JF - Acta Crystallographica Section C-Crystal Structure Communications

ER -

(1RS,2RS)-N,N '-Bis(4-nitrophenylmethylene)cyclohexane-1,2-diamine: complex sheets built from C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds

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