1D-coordination polymer formed by structural conversion of an oxazolidine ligand in reaction with the copper(II) halides

Zahra Mardani; Vali Golsanamlou; Zahra Jabbarzadeh; Keyvan Moeini; Cameron Carpenter-Warren; Alexandra M.Z. Slawin; J. Derek Woollins

doi:10.5012/jkcs.2018.62.5.372

1D-coordination polymer formed by structural conversion of an oxazolidine ligand in reaction with the copper(II) halides

Zahra Mardani, Vali Golsanamlou, Zahra Jabbarzadeh, Keyvan Moeini, Cameron Carpenter-Warren, Alexandra M.Z. Slawin, J. Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

A 1D-coordination polymer of 1D-{Cu(μ-picolinato)₂}{Hakimi, 2012 #73}_n (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and CuCl₂ or CuBr₂. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product-1D-{Cu(μ-picolinato)₂}n (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a CuN₂O₄ environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.

Original language	English
Pages (from-to)	372-376
Number of pages	5
Journal	Journal of the Korean Chemical Society
Volume	62
Issue number	5
DOIs	https://doi.org/10.5012/jkcs.2018.62.5.372
Publication status	Published - 20 Oct 2018

Keywords

Coordination polymer
Copper complex
Oxazolidine
Picolinate
X-Ray crystal structure

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@article{b0fa423610004b87a002f44a17361265,

title = "1D-coordination polymer formed by structural conversion of an oxazolidine ligand in reaction with the copper(II) halides",

abstract = "A 1D-coordination polymer of 1D-\{Cu(μ-picolinato)2\}\{Hakimi, 2012 \#73\}n (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and CuCl2 or CuBr2. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product-1D-\{Cu(μ-picolinato)2\}n (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a CuN2O4 environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.",

keywords = "Coordination polymer, Copper complex, Oxazolidine, Picolinate, X-Ray crystal structure",

author = "Zahra Mardani and Vali Golsanamlou and Zahra Jabbarzadeh and Keyvan Moeini and Cameron Carpenter-Warren and Slawin, \{Alexandra M.Z.\} and \{Derek Woollins\}, J.",

note = "Publication cost of this paper was supported by the Korean Chemical Society.",

year = "2018",

month = oct,

day = "20",

doi = "10.5012/jkcs.2018.62.5.372",

language = "English",

volume = "62",

pages = "372--376",

journal = "Journal of the Korean Chemical Society",

issn = "1017-2548",

publisher = "Korean Chemical Society",

number = "5",

}

TY - JOUR

T1 - 1D-coordination polymer formed by structural conversion of an oxazolidine ligand in reaction with the copper(II) halides

AU - Mardani, Zahra

AU - Golsanamlou, Vali

AU - Jabbarzadeh, Zahra

AU - Moeini, Keyvan

AU - Carpenter-Warren, Cameron

AU - Slawin, Alexandra M.Z.

AU - Derek Woollins, J.

N1 - Publication cost of this paper was supported by the Korean Chemical Society.

PY - 2018/10/20

Y1 - 2018/10/20

N2 - A 1D-coordination polymer of 1D-{Cu(μ-picolinato)2}{Hakimi, 2012 #73}n (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and CuCl2 or CuBr2. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product-1D-{Cu(μ-picolinato)2}n (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a CuN2O4 environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.

AB - A 1D-coordination polymer of 1D-{Cu(μ-picolinato)2}{Hakimi, 2012 #73}n (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and CuCl2 or CuBr2. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product-1D-{Cu(μ-picolinato)2}n (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a CuN2O4 environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.

KW - Coordination polymer

KW - Copper complex

KW - Oxazolidine

KW - Picolinate

KW - X-Ray crystal structure

UR - https://www.scopus.com/pages/publications/85054281585

U2 - 10.5012/jkcs.2018.62.5.372

DO - 10.5012/jkcs.2018.62.5.372

M3 - Article

AN - SCOPUS:85054281585

SN - 1017-2548

VL - 62

SP - 372

EP - 376

JO - Journal of the Korean Chemical Society

JF - Journal of the Korean Chemical Society

IS - 5

ER -

1D-coordination polymer formed by structural conversion of an oxazolidine ligand in reaction with the copper(II) halides

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Keywords

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