TY - JOUR
T1 - 1D-coordination polymer formed by structural conversion of an oxazolidine ligand in reaction with the copper(II) halides
AU - Mardani, Zahra
AU - Golsanamlou, Vali
AU - Jabbarzadeh, Zahra
AU - Moeini, Keyvan
AU - Carpenter-Warren, Cameron
AU - Slawin, Alexandra M.Z.
AU - Derek Woollins, J.
N1 - Publication cost of this paper was supported by the Korean Chemical Society.
PY - 2018/10/20
Y1 - 2018/10/20
N2 - A 1D-coordination polymer of 1D-{Cu(μ-picolinato)2}{Hakimi, 2012 #73}n (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and CuCl2 or CuBr2. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product-1D-{Cu(μ-picolinato)2}n (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a CuN2O4 environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.
AB - A 1D-coordination polymer of 1D-{Cu(μ-picolinato)2}{Hakimi, 2012 #73}n (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and CuCl2 or CuBr2. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product-1D-{Cu(μ-picolinato)2}n (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a CuN2O4 environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.
KW - Coordination polymer
KW - Copper complex
KW - Oxazolidine
KW - Picolinate
KW - X-Ray crystal structure
U2 - 10.5012/jkcs.2018.62.5.372
DO - 10.5012/jkcs.2018.62.5.372
M3 - Article
AN - SCOPUS:85054281585
SN - 1017-2548
VL - 62
SP - 372
EP - 376
JO - Journal of the Korean Chemical Society
JF - Journal of the Korean Chemical Society
IS - 5
ER -