1,4-Oxazine

R Alan Aitken; Kati Marianne Aitken; Phillip G Carruthers; Marc-Alexandre Jean; Alexandra Martha Zoya Slawin

doi:10.1039/c3cc47801g

1,4-Oxazine

R Alan Aitken, Kati Marianne Aitken, Phillip G Carruthers, Marc-Alexandre Jean, Alexandra Martha Zoya Slawin

Research output: Contribution to journal › Article › peer-review

Abstract

The fundamental heterocyclic compound 1,4-oxazine has been generated using FVP. It is the first parent heterocycle among all the possible isomeric oxazines, thiazines and their heavier atom analogues to be characterised spectroscopically, and is shown to exist in solution entirely as the 4H-isomer. X-ray structure determination of the N-Boc precursor shows significant deviations from theoretically predicted geometric parameters.

Original language	English
Pages (from-to)	11367-11369
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	97
Early online date	23 Oct 2013
DOIs	https://doi.org/10.1039/c3cc47801g
Publication status	Published - 2013

Keywords

Heterocyclic compound
FVP
4H-isomer
N-Boc precursor
Isomeric oxazines
Thiazine

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10.1039/c3cc47801g

13CC11367
Copyright 2013, the Authors. This open access article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
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title = "1,4-Oxazine",

abstract = "The fundamental heterocyclic compound 1,4-oxazine has been generated using FVP. It is the first parent heterocycle among all the possible isomeric oxazines, thiazines and their heavier atom analogues to be characterised spectroscopically, and is shown to exist in solution entirely as the 4H-isomer. X-ray structure determination of the N-Boc precursor shows significant deviations from theoretically predicted geometric parameters.",

keywords = "Heterocyclic compound , FVP, 4H-isomer, N-Boc precursor, Isomeric oxazines, Thiazine",

author = "Aitken, {R Alan} and Aitken, {Kati Marianne} and Carruthers, {Phillip G} and Marc-Alexandre Jean and Slawin, {Alexandra Martha Zoya}",

year = "2013",

doi = "10.1039/c3cc47801g",

language = "English",

volume = "49",

pages = "11367--11369",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "97",

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TY - JOUR

T1 - 1,4-Oxazine

AU - Aitken, R Alan

AU - Aitken, Kati Marianne

AU - Carruthers, Phillip G

AU - Jean, Marc-Alexandre

AU - Slawin, Alexandra Martha Zoya

PY - 2013

Y1 - 2013

N2 - The fundamental heterocyclic compound 1,4-oxazine has been generated using FVP. It is the first parent heterocycle among all the possible isomeric oxazines, thiazines and their heavier atom analogues to be characterised spectroscopically, and is shown to exist in solution entirely as the 4H-isomer. X-ray structure determination of the N-Boc precursor shows significant deviations from theoretically predicted geometric parameters.

AB - The fundamental heterocyclic compound 1,4-oxazine has been generated using FVP. It is the first parent heterocycle among all the possible isomeric oxazines, thiazines and their heavier atom analogues to be characterised spectroscopically, and is shown to exist in solution entirely as the 4H-isomer. X-ray structure determination of the N-Boc precursor shows significant deviations from theoretically predicted geometric parameters.

KW - Heterocyclic compound

KW - FVP

KW - 4H-isomer

KW - N-Boc precursor

KW - Isomeric oxazines

KW - Thiazine

U2 - 10.1039/c3cc47801g

DO - 10.1039/c3cc47801g

M3 - Article

SN - 1359-7345

VL - 49

SP - 11367

EP - 11369

JO - Chemical Communications

JF - Chemical Communications

IS - 97

ER -

1,4-Oxazine

Abstract

Keywords

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