1,3-dioxoles and 1,3-oxathioles

R Alan Aitken

doi:10.1016/B978-0-12-818655-8.00147-5

1,3-dioxoles and 1,3-oxathioles

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Abstract

Developments in the chemistry of five-membered ring heterocycles containing two non-adjacent oxygens or one oxygen and one sulfur in the period 2008–2020 are reviewed. Application of theoretical and structural methods to these compounds is described including X-ray structure determination and NMR. The major reactions of 1,3-dioxolanes and 1,3-oxathiole systems are discussed. Methods for the synthesis of all the compounds are systematically covered. There has been a particular focus on the reaction of epoxides with CO₂ to give dioxolanones and the large number of new catalysts for this process are surveyed. Dioxolane-containing systems have also made a significant impact in polymer science and this and other applications are covered.

Original language	English
Title of host publication	Comprehensive heterocyclic chemistry IV
Subtitle of host publication	a review of the literature 2008-2021
Editors	R. A. Aitken
Place of Publication	Amsterdam
Publisher	Elsevier (incl. Pergamon )
Chapter	10
Pages	724-765
Number of pages	42
Volume	4
ISBN (Electronic)	9780128186565
ISBN (Print)	9780323912679, 9780128186558
DOIs	https://doi.org/10.1016/B978-0-12-818655-8.00147-5
Publication status	Published - 23 Nov 2021

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10.1016/B978-0-12-818655-8.00147-5

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AB - Developments in the chemistry of five-membered ring heterocycles containing two non-adjacent oxygens or one oxygen and one sulfur in the period 2008–2020 are reviewed. Application of theoretical and structural methods to these compounds is described including X-ray structure determination and NMR. The major reactions of 1,3-dioxolanes and 1,3-oxathiole systems are discussed. Methods for the synthesis of all the compounds are systematically covered. There has been a particular focus on the reaction of epoxides with CO2 to give dioxolanones and the large number of new catalysts for this process are surveyed. Dioxolane-containing systems have also made a significant impact in polymer science and this and other applications are covered.

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M3 - Chapter

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BT - Comprehensive heterocyclic chemistry IV

A2 - Aitken, R. A.

PB - Elsevier (incl. Pergamon )

CY - Amsterdam

ER -

1,3-dioxoles and 1,3-oxathioles

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