1,2-Migration of the trimethylsilyl group in free radicals

Joanna M. Harris; Iain MacInnes; John C. Walton; Bernard Maillard

doi:10.1016/0022-328X(91)86490-H

1,2-Migration of the trimethylsilyl group in free radicals

Joanna M. Harris^*, Iain MacInnes, John C. Walton, Bernard Maillard

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

EPR spectroscopic observations and product studies showed that the trimethylsilyl group undergoes 1,2-migration from carbon to nitrogen in aminyl radicals, Me₃SiCh₂O^.→^.CH₂NHSiMe₃, and from carbon to oxygen in alkoxyl radicals, Me₃SiCh₂O^.→^.CH₂OSiMe₃.

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	403
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(91)86490-H
Publication status	Published - 19 Feb 1991

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@article{e99d50c4f45d4a45be6b2af3ace0c5b0,

title = "1,2-Migration of the trimethylsilyl group in free radicals",

abstract = "EPR spectroscopic observations and product studies showed that the trimethylsilyl group undergoes 1,2-migration from carbon to nitrogen in aminyl radicals, Me3SiCh2O.→.CH2NHSiMe3, and from carbon to oxygen in alkoxyl radicals, Me3SiCh2O.→.CH2OSiMe3.",

author = "Harris, {Joanna M.} and Iain MacInnes and Walton, {John C.} and Bernard Maillard",

year = "1991",

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journal = "Journal of Organometallic Chemistry",

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AU - Harris, Joanna M.

AU - MacInnes, Iain

AU - Walton, John C.

AU - Maillard, Bernard

PY - 1991/2/19

Y1 - 1991/2/19

N2 - EPR spectroscopic observations and product studies showed that the trimethylsilyl group undergoes 1,2-migration from carbon to nitrogen in aminyl radicals, Me3SiCh2O.→.CH2NHSiMe3, and from carbon to oxygen in alkoxyl radicals, Me3SiCh2O.→.CH2OSiMe3.

AB - EPR spectroscopic observations and product studies showed that the trimethylsilyl group undergoes 1,2-migration from carbon to nitrogen in aminyl radicals, Me3SiCh2O.→.CH2NHSiMe3, and from carbon to oxygen in alkoxyl radicals, Me3SiCh2O.→.CH2OSiMe3.

UR - http://www.scopus.com/inward/record.url?scp=0001866853&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(91)86490-H

DO - 10.1016/0022-328X(91)86490-H

M3 - Article

AN - SCOPUS:0001866853

SN - 0022-328X

VL - 403

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

1,2-Migration of the trimethylsilyl group in free radicals

Abstract

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