Underpinning Mechanistic Studies of NHC-Organocatalysis: A Breslow Intermediate Reactivity Scale

Smith, Andrew David (PI)

School of Chemistry

Project: Standard

Acronym	Underpinning Mechanistic Studies
Status	Finished
Effective start/end date	1/04/19 → 31/12/22

Funding

EPSRC: £398,307.60

7 Article

Isothiourea-catalysed enantioselective synthesis of phosphonate-functionalised β-lactones
Platt, F. M., Wang, Y., Cordes, D. B., McKay, A. P., Slawin, A. M. Z., Panchal, H. & Smith, A. D., 6 Mar 2025, (E-pub ahead of print) In: Chemical Science. Advance Articles, 9 p.
Research output: Contribution to journal › Article › peer-review

Open Access
File
α-Phenylthioaldehydes for the effective generation of acyl azolium and azolium enolate intermediates
Ewing, P., Majhi, P., Prentice, C., Young, C. M., Van Rees, K., Arnold, P., Zysman-Colman, E. & Smith, A. D., 14 May 2024, In: Chemical Science. 24, 15, p. 9369-9375
Research output: Contribution to journal › Article › peer-review

Open Access
File
Probing regio- and enantioselectivity in the formal [2+2] cycloaddition of C(1)-alkyl ammonium enolates with - and ,-substituted tri-fluoromethylenones
Wang, Y., Young, C. M., Cordes, D. B., Slawin, A. M. Z. & Smith, A. D., 16 Jun 2023, In: The Journal of Organic Chemistry. 88, 12, p. 7784-7799 16 p.
Research output: Contribution to journal › Article › peer-review

Open Access
File

data underpinning "a-Phenylthioaldehydes for the effective generation of acyl azolium and azolium enolate intermediates"
Smith, A. D. (Creator), Majhi, P. (Creator), Zysman-Colman, E. (Creator), Prentice, C. (Creator), Ewing, P. (Creator), Young, C. M. (Creator), Van Rees, K. (Creator) & Arnold, P. (Creator), University of St Andrews, 30 Jul 2024
DOI: 10.17630/b0dfa038-03b4-4054-a2a3-72a4e1593b16
Dataset

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Kinetic and Structure-Activity Studies of the Triazolium Ion- catalyzed Intramolecular Stetter Reaction (dataset)
Smith, A. D. (Creator) & Young, C. M. (Creator), University of St Andrews, 2 Jun 2021
DOI: 10.17630/7b18dcdd-72a3-4b26-909b-25ccd31cd58c
Dataset

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data underpinning "Probing Regio- and Enantioselectivity in the Formal [2+2] Cycloaddi-tion of C(1)-Alkyl Ammonium Enolates with β- and α,β-Substituted Trifluoromethylenones"
Smith, A. D. (Creator), Wang, Y. (Owner) & Young, C. M. (Owner), University of St Andrews, 17 May 2023
DOI: 10.17630/ec54103f-32b7-422b-8e9a-f2c1f623065c, http://hdl.handle.net/10023/26954
Dataset

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