Stable Phosphorous Cenred Radicals and Odd Electron Bonds

Research output

Research output per year 2009 2009 2011 2012 2014 2015 2016

• 12 Article
• 2 Review article

Research output per year

Research output per year

Search results

• 2016

  Spontaneous dehydrocoupling in peri-substituted phosphine-borane adducts

  Taylor, L. J., Surgenor, B. A., Wawrzyniak, P., Ray, M. J., Cordes, D. B., Slawin, A. M. Z. & Kilian, P., 7 Feb 2016, In: Dalton Transactions. 45, 5, p. 1976-1986

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Borane 100%
  • Dihydrogen 20%
  • Phosphonium 20%
  • Acenaphthene 20%
  • Single Crystalline Solid 20%
  6 Citations (Scopus)

  5 Downloads (Pure)
• 2015

  A structural, spectroscopic and computational examination of the dative interaction in constrained phosphine–stibines and phosphine–stiboranes

  Chalmers, B. A., Buehl, M., Athukorala Arachchige, K. S., Slawin, A. M. Z. & Kilian, P., 11 May 2015, In: Chemistry - A European Journal. 21, 20, p. 7520-7531

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Lewis acidity 100%
  • Bond Length 50%
  • Antimony 50%
  • Density Functional Theory 50%
  • Acenaphthene 50%
  37 Citations (Scopus)

  11 Downloads (Pure)

• Hydride abstraction and deprotonation – an efficient route to low co-ordinate phosphorus and arsenic species

  Taylor, L. J., Buehl, M., Wawrzyniak, P., Chalmers, B. A., Woollins, J. D., Slawin, A. M. Z., Fuller, A. & Kilian, P., 2015, In: European Journal of Inorganic Chemistry. Early view

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Phosphorane 100%
  • Phosphorus 100%
  • Deprotonation 100%
  • Lewis Base 50%
  • Dehydrogenation 50%
  12 Citations (Scopus)

  44 Downloads (Pure)
• 2014

  Geometrically enforced donor-facilitated dehydrocoupling leading to an isolable arsanylidine-phosphorane

  Chalmers, B. A., Buehl, M., Athukorala Arachchige, K. S., Slawin, A. M. Z. & Kilian, P., Apr 2014, In: Journal of the American Chemical Society. 136, 17, p. 6247-6250

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Donor 100%
  • Phosphorane 100%
  • formation 100%
  • Arsenic Atom 50%
  • Dehydrogenation 50%
  39 Citations (Scopus)

  8 Downloads (Pure)

• Reactivity profile of a peri-substitution-stabilized phosphanylidene-phosphorane: synthetic, structural, and computational studies

  Surgenor, B. A., Chalmers, B. A., Athukorala Arachchige, K. S., Slawin, A. M. Z., Woollins, J. D., Buehl, M. & Kilian, P., 9 Jun 2014, In: Inorganic Chemistry. 53, 13, p. 6856–6866 11 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File

  • Phosphorane 100%
  • formation 100%
  • Hyperconjugation 66%
  • Metal Atom 33%
  • Natural Bond Orbital Analysis 33%
  30 Citations (Scopus)

  18 Downloads (Pure)
• 2012

  Isolable phosphanylidene phosphorane with a sterically accessible two-coordinate phosphorus atom

  Surgenor, B. A., Buehl, M., Slawin, A. M. Z., Woollins, J. D. & Kilian, P., 1 Oct 2012, In: Angewandte Chemie International Edition. 51, 40, p. 10150-10153 4 p.

  Research output: Contribution to journal › Article › peer-review

  Open Access

  File
  68 Citations (Scopus)

  10 Downloads (Pure)

• Synthetic and computational study of geminally bis(supermesityl) substituted phosphorus compounds

  Fleming, C. G. E., Slawin, A. M. Z., Arachchige, K. S. A., Randall, R., Buehl, M. & Kilian, P., Nov 2012, In: Dalton Transactions. 42, 5, p. 1437-1450 14 p.

  Research output: Contribution to journal › Article › peer-review

  • Phosphorus Compound 100%
  • Phosphine Oxide 100%
  • Electrophile 50%
  • Chemistry 50%
  • DFT-B3LYP Calculation 50%
  13 Citations (Scopus)
• 2011

  1,2-Diphosphaacenaphthene 1,2-Dications: Synthetic, Stereochemical and Computational Study of the Stabilising Role of Naphthalene-1,8-diyl Backbone

  Somisara, D. M. U. K., Buehl, M., Lebl, T., Richardson, N. V., Slawin, A. M. Z., Woollins, J. D. & Kilian, P., 25 Feb 2011, In: Chemistry - A European Journal. 17, 9, p. 2666-2677 12 p.

  Research output: Contribution to journal › Article › peer-review

  • Naphthalene 100%
  • Single Crystalline Solid 50%
  • Triflate 25%
  • DFT-B3LYP Calculation 25%
  • Phosphorus 25%
  22 Citations (Scopus)

• Prediction of a New Delocalised Bonding Motif between Group 15 or Group 16 Atoms

  Buehl, M., Kilian, P. & Woollins, J. D., 12 Sept 2011, In: ChemPhysChem. 12, 13, p. 2404-2407 4 p.

  Research output: Contribution to journal › Article › peer-review
  21 Citations (Scopus)
• 2010

  Syntheses and characterization of bis(trifluoromethyl)phosphino naphthalenes and acenaphthenes

  Wawrzyniak, P., Slawin, A. M. Z., Woollins, J. D. & Kilian, P., 2010, In: Dalton Transactions. 39, 1, p. 85-92 8 p.

  Research output: Contribution to journal › Article › peer-review

  • Trifluoromethylation 100%
  • Acenaphthene 100%
  • Naphthalene 33%
  • Single Crystal X-Ray Diffraction 33%
  14 Citations (Scopus)
• 2009

  Intramolecular Phosphine-Phosphine Donor-Acceptor Complexes

  Wawrzyniak, P., Fuller, A., Slawin, A. M. Z. & Kilian, P., 16 Mar 2009, In: Inorganic Chemistry. 48, 6, p. 2500-2506 7 p.

  Research output: Contribution to journal › Article › peer-review

  • Donor 100%
  • Phosphonium 100%
  • Mechanistic Study 50%
  • Nucleophile 50%
  • Acenaphthene 50%
  52 Citations (Scopus)

• Phosphorus peri-bridged acenaphthenes: efficient syntheses, characterisation and quaternization reactions

  Wawrzyniak, P., Slawin, A. M. Z., Fuller, A. L., Woollins, J. D. & Kilian, P., 14 Oct 2009, In: Dalton Transactions. 38, p. 7883-7884 2 p.

  Research output: Contribution to journal › Article › peer-review

  • Acenaphthene 100%
  • Phosphorus 100%
  • Quaternization 100%
  • Tertiary Phosphine 50%
  • X-Ray Diffraction 50%
  10 Citations (Scopus)