Exploiting Chalcogen Bonding and Non-Covalent Interactions in Isochalcogenourea Catalysis: Catalyst Preparation, Mechanistic Studies and Applications

Smith, Andrew (PI)

School of Chemistry

Project: Standard

Acronym	Exploiting Chalcogen Bonding and Non
Status	Finished
Effective start/end date	1/11/20 → 31/10/23

12 Article

The catalytic enantioselective [1,2]-Wittig rearrangement cascade of allylic ethers
Kang, T., O'Yang, J., Kasten, K., Allsop, S. S., Lewis-Atwell, T., Farrar, E. H. E., Juhl, M., Cordes, D. B., McKay, A. P., Grayson, M. N. & Smith, A. D., 6 Jan 2026, (E-pub ahead of print) In: Nature Chemistry. AOP, 11 p.
Research output: Contribution to journal › Article › peer-review

Open Access
File
From oxygen to tellurium: the impact of the chalcogen on nucleophilicities and basicities of isochalcogenourea catalysts
Stockhammer, L., Kasten, K., Eitzinger, A., Vogl, L. S., Piringer, M., Weinzierl, D., Ofial, A. R., Smith, A. D. & Waser, M., 23 Oct 2025, (E-pub ahead of print) In: Angewandte Chemie International Edition. Early View, 15 p., e202514865.
Research output: Contribution to journal › Article › peer-review

Open Access
File
In-cage recombination facilitates the enantioselective organocatalytic [1,2]-rearrangement of allylic ammonium ylides
Hartley, W., Kasten, K., Greenhalgh, M. D., Feoktistova, T., Wise, H., Laddusaw, J., Frost, A. B., Ng, S., Slawin, A. M. Z., Bode, B. E., Cheong, P. & Smith, A. D., 8 Jan 2025, In: Journal of the American Chemical Society. 147, 1, p. 1101-1111 11 p.
Research output: Contribution to journal › Article › peer-review

Open Access
File

Enantioselective Synthesis in Continuous Flow: Polymer Supported Isothiourea Catalyzed Enantioselective Michael Addition-Lactamisation with Azaaryl ketones (dataset)
Smith, A. D. (Creator), Zhou, Z. (Creator), Kasten, K. (Creator), Kang, T. (Creator) & Cordes, D. B. (Creator), University of St Andrews, 15 Mar 2024
DOI: 10.17630/9eec7d03-0634-4239-ab47-bdfe105813ec
Dataset

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data underpinning "Isothiourea-Catalyzed [2+2] Cycloaddition of C(1)-Ammonium Enolates and N-Alkyl Isatins"
Smith, A. D. (Creator), Kasten, K. (Creator), Young, C. M. (Creator) & Slawin, A. M. Z. (Creator), University of St Andrews, 25 Jul 2022
DOI: 10.17630/40852daa-0199-41e9-afb0-600a47d25ab9
Dataset

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Data underpinning "Unveiling the impact of CF2 motif in the Isothiourea Catalyst Skeleton: Evaluating C(3)-F2-HBTM and its Catalytic Activity"
Smith, A. D. (Creator), Westwood, M. (Creator) & Kasten, K. (Creator), University of St Andrews, 25 Sept 2023
DOI: 10.17630/71039bf0-a0c5-44da-9934-0759efd35343
Dataset

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