Personal profile
Research overview
Our research aims to combine high-resolution multinuclear Nuclear Magnetic Resonance (NMR) spectroscopy with periodic first-principles calculations to investigate structure, order and dynamics in the solid state. Research involves the development of new experiments, implementation and improvement of existing experiments and the application to systems of interest in chemistry, geology and materials science. Particular emphasis is given to nuclei which possess a nuclear electric quadrupole moment, such as 17-O, 23-Na or 27-Al, which account for over 75% of all NMR-accessible nuclides. Current areas of interest include high-pressure minerals, microporous framework materials and ceramic materials proposed for the encapsulation of nuclear waste.
For more information see the SEA group website: http://chemistry.st-andrews.ac.uk/staff/sa/group/Site/Home.html
Academic/Professional Qualification
MChem Hertford College, University of Oxford
MA University of Oxford;
DPhil Physical and Theoretical Chemistry Laboratory, University of Oxford
Fellow of the Royal Society of Edinburgh (FRSE)
Fellow ISMAR
Fellow of the Royal Society of Chemistry (FRSC)
Member of the Institute of Physics (MinstP)
Member of the Mineralogical Society of Great Britain
Biography
Professor Ashbrook studied for an MChem Chemistry degree at Hertford College, University of Oxford, before completing her DPhil, also at Oxford in the Physical and Theoretical Chemistry Laboratory, under the supervision of Stephen Wimperis. After a postdoc at the Unviersity of Exeter, Professor Ashbrook was awarded a Royal Society Dorothy Hodgkin Fellowship, which she held in the Department of Earth Sciences at the University of Cambridge. During this time she also held the Charles and Katherine Darwin Research Fellowship at Darwin College. Professor Ashbrook moved to St Andrews in 2005, when she was awarded an RCUK Academic Fellowship, and was promoted to Reader in 2009 and Professor in 2013. She was awarded a Royal Society Wolfson Merit Award in 2015, and elected FRSE in 2016. In 2025, she was elected a fellow of the International Soceity of Magnetic Resonance. She has also been awarded the RSE Makdougall Brisbane Medal (2012) and Lord Kelvin Prize (2023), the RSC Harrison Prize (2004), Marlow Award (2011), Corday Morgan Award (2015) and Bourke-Liversidge Award (2021). In 2017, she was awarded a Suffrage Science Award. Professor Ashbrook has also acted as the Professorial Senate Assessor for Science and Medicine on University Court.
Profile Keywords
Solid-state NMR method development; Application of NMR to the study of inoragnic materials; First-principles calcualtion of NMR parameters; Solid-state NMR of microporous materials
Teaching activity
CH1301 The Impact of Chemistry
CH1401 Introductory Inorganic and Physical Chemistry
CH1402 Inorganic and Physical Chemistry 1
CH2701 Physical Chemistry 2
CH3431 Chemistry workshop
CH4717 Fundamentals of Spectroscopy of Molecules and Solids
CH444/CH5441 Honours Project Assessment
Expertise related to UN Sustainable Development Goals
In 2015, UN member states agreed to 17 global Sustainable Development Goals (SDGs) to end poverty, protect the planet and ensure prosperity for all. This person’s work contributes towards the following SDG(s):
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SDG 3 Good Health and Well-being
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SDG 7 Affordable and Clean Energy
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SDG 14 Life Below Water
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Collaborations and top research areas from the last five years
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A picture of disorder in hydrous wadsleyite – under the combined microscope of solid-state NMR spectroscopy and ab initio random structure searching
McKay, D., Moran, R. F., Dawson, D. M., Griffin, J. M., Sturniolo, S., Pickard, C. J., Berry, A. J. & Ashbrook, S. E., 20 Feb 2019, In: Journal of the American Chemical Society. 141, 7, p. 3024–3036 13 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile -
Hydrolytic stability in hemilabile metal–organic frameworks
McHugh, L. N., McPherson, M. J., McCormick, L. J., Morris, S. A., Wheatley, P. S., Teat, S. J., McKay, D., Dawson, D. M., Sansome, C. E. F., Ashbrook, S. E., Stone, C. A., Smith, M. W. & Morris, R. E., Nov 2018, In: Nature Chemistry. 10, 11, p. 1096–1102 7 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile -
Perspective: current advances in solid-state NMR spectroscopy
Ashbrook, S. E. & Hodgkinson, P., 28 Jul 2018, In: Journal of Chemical Physics. 149, 4, 040901.Research output: Contribution to journal › Review article › peer-review
Open AccessFile -
17O solid-state NMR spectroscopy of A2B2O7 oxides: quantitative isotopic enrichment and spectral acquisition?
Fernandes, A., Moran, R., Sneddon, S., Dawson, D. M., McKay, D., Bignami, G. P. M., Blanc, F., Whittle, K. & Ashbrook, S. E., 14 Feb 2018, (E-pub ahead of print) In: RSC Advances. 8, 13, p. 7089-7101Research output: Contribution to journal › Article › peer-review
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Cost-effective 17O enrichment and NMR spectroscopy of mixed-metal terephthalate metal-organic frameworks
Bignami, G. P. M., Davis, Z. H., Dawson, D. M., Morris, S. A., Russell, S. E., McKay, D., Parke, R. E., Iuga, D., Morris, R. E. & Ashbrook, S. E., 28 Jan 2018, In: Chemical Science. 9, 4, p. 850-859Research output: Contribution to journal › Article › peer-review
Open AccessFile
Datasets
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Mechanistic insights into Cs-ion exchange in the zeolite chabazite from in situ powder X-ray diffraction (dataset)
Parsons, D. (Creator), Nearchou, A. (Creator), Griffiths, B. (Creator), Ashbrook, S. E. (Creator) & Hriljac, J. (Creator), University of St Andrews, 25 Jun 2024
DOI: 10.17630/b1e57582-c20c-4e7a-bfbb-e241428ebac3
Dataset
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Exploiting In Situ NMR Spectroscopy to Understand Non-Traditional Methods for Zeolite Synthesis (dataset)
Kelly, N. (Creator), Borthwick, E. A. L. (Creator), Lawrence, G. (Creator), Wheatley, P. S. (Creator), Hughes, C. E. (Creator), Harris, K. D. M. (Creator), Morris, R. E. (Creator) & Ashbrook, S. E. (Creator), University of St Andrews, 19 Feb 2025
DOI: 10.17630/4d38d0ea-6238-4ae8-9055-ed92a03979c6
Dataset
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Understanding the Synthesis and Reactivity of ADORable Zeolites using NMR Spectroscopy (dataset)
Ashbrook, S. E. (Creator), Morris, R. E. (Creator) & Rice, C. M. (Creator), University of St Andrews, 30 Sept 2022
DOI: 10.17630/d82e58e4-b4a0-40b3-8156-5cbf80eeea72
Dataset
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An NMR Crystallographic Characterisation of Solid (+)-Usnic Acid (dataset)
Dawson, D. M. (Creator), Smellie, I. (Creator) & Ashbrook, S. E. (Creator), University of St Andrews, 23 May 2024
DOI: 10.17630/6593874e-7f56-4530-b1dc-49134f3114ce
Dataset
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Alkaline attack of boro-alumino-silicate glass: New insights of the molecular mechanism of cold consolidation and new applications (dataset)
Tameni, G. (Creator), Lago, D. (Creator), Kaňková, H. (Creator), Buňová, L. (Creator), Kraxner, J. (Creator), Galusek , D. (Creator), Dawson, D. M. (Creator), Ashbrook, S. E. (Creator) & Bernardo, E. (Creator), University of St Andrews, 4 Mar 2025
DOI: 10.17630/0db59a37-351a-4e4f-8e01-f3e662b03fdc
Dataset
File
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NMR at 1.2GHz: A World Leading UK: NMR at 1.2GHz: A World Leading UK Facility To Deliver Advances In Biology, Chemistry & Material Science
Ashbrook, S. E. (PI)
1/01/23 → 31/12/27
Project: Standard
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Decarbonising the Acrylic Value: Decarbonising The Acrylic Value Chain Via Resource Circularity
Webb, P. (PI) & Ashbrook, S. E. (CoI)
1/04/21 → 31/03/26
Project: Standard
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NMR Crystallography: Collaborative Computational Project in NMR Crystallography
Ashbrook, S. E. (PI)
6/05/20 → 5/05/25
Project: Standard
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NMR National Research Facility: The UK High-Field Solid-State NMR National Research Facility
Ashbrook, S. E. (PI)
5/01/20 → 4/01/25
Project: Standard
Activities
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National Management Committee for the UK 850 MHz Solid-State NMR Facility (External organisation)
Ashbrook, S. E. M. (Participant)
2008 → 2014Activity: Membership types › Membership of research network
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Mineralogical Society of Great Britain and Ireland (External organisation)
Ashbrook, S. E. M. (Participant)
2010 → …Activity: Membership types › Membership in special-interest organisation
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RSC Tayside local section (External organisation)
Ashbrook, S. E. M. (Participant)
2019 → 2025Activity: Membership types › Membership of peer review panel or committee
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RSE Fellowship Panel (Chemistry and Earth Sciences) (External organisation)
Ashbrook, S. E. M. (Participant)
2019 → 2022Activity: Membership types › Membership of peer review panel or committee
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Magnetic Resonance in Chemistry (Journal)
Ashbrook, S. E. M. (Member of editorial board)
2019 → …Activity: Publication peer-review and editorial work types › Editor of research journal
Prizes
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Royal Society of Chemistry, Harrison Prize
Ashbrook, S. E. M. (Recipient), 2004
Prize: Prize (including medals and awards)
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BRSG-NMRDG Early Career Prize for Magnetic Resonance
Ashbrook, S. E. M. (Recipient), 2009
Prize: Prize (including medals and awards)
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Corday-Morgan Prize 2015
Ashbrook, S. E. M. (Recipient), 2015
Prize: Prize (including medals and awards)
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Fellow of the Royal Society of Edinburgh
Ashbrook, S. E. M. (Recipient), 2016
Prize: Election to learned society