Personal profile
Research overview
My research focuses on the structural solid state chemistry of inorganic materials, in particular the understanding of the structure-composition-property relationships in these materials. Wide use is made of diffraction methods, which regularly involves visits to central facilities outside St Andrews ; eg synchrotron sources and neutron sources at Diamond and ISIS, Oxford. My group design and synthesise new compounds which are of interest for a variety of applications. We also delve deeper into the understanding of well-established functional materials, in order to predict new improvements to them, through chemistry. Current interests focus on ferroelectric, magnetic and multiferroic (ie simultaneously electrically and magnetically active) materials, including both inorganic oxides, fluorides and hybrid inorganic-organic analogues.
Research overview
For further information see our Group website
Industrial relevance
ferroelectrics, superconductors, low thermal expansion ceramics, batteries, fuel cells, sensors, heterogeneous catalysis, powder diffraction methods.
Academic/Professional Qualification
Biography
Professor Lightfoot studied for an MA at Oxford University, followed by a D.Phil (Oxford) under the supervision of Prof Tony Cheetham. After short post-doctoral periods at Leeds and Argonne (USA) hejoined the School in 1990, first as a Post-doctoral Fellow (with Peter Bruce) and subsequently Lecturer (1994), Reader (2000) and Professor (2009).
Profile Keywords
Inorganic and hybrid solids; ferroic materials; crystallography and structure-property relationships
Teaching activity
Professor Lightfoot is currently Director of Teaching in the School of Chemistry and oversees all aspects of the School's undergraduate teaching and degree courses. He also teaches inorganic chemistry and related fields at all levels, for example Solid State Chemistry in CH2501, Blockbuster Solids in CH5518 and Crystallography in the CH4431 research Skills Lab.
Expertise related to UN Sustainable Development Goals
In 2015, UN member states agreed to 17 global Sustainable Development Goals (SDGs) to end poverty, protect the planet and ensure prosperity for all. This person’s work contributes towards the following SDG(s):
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SDG 7 Affordable and Clean Energy
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- 1 Similar Profiles
Collaborations and top research areas from the last five years
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Gapless Spin Liquid Ground State in the S=1/2 Vanadium Oxyfluoride Kagome Antiferromagnet [NH4 ]2[C7H14N][V7O6F18]
Clark, L., Orain, J. C., Bert, F., De Vries, M. A., Himeur, F. H., Morris, R. E., Lightfoot, P., Lord, J. S., Telling, M. T. F., Bonville, P., Attfield, J. P., Mendels, P. & Harrison, A., 16 May 2013, In: Physical Review Letters. 110, 20, 5 p., 207208.Research output: Contribution to journal › Article › peer-review
Open AccessFile -
New Twists on the Perovskite Theme: Crystal Structures of the Elusive Phases R and S of NaNbO3
Peel, M. D., Thompson, S. P., Daoud-Aladine, A., Ashbrook, S. E. & Lightfoot, P., 18 Jun 2012, In: Inorganic Chemistry. 51, 12, p. 6876-6889 14 p.Research output: Contribution to journal › Article › peer-review
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Magnetically driven dielectric and structural behavior in Bi0.5La0.5FeO3
Kavanagh, C. M., Goff, R. J., Daoud-Aladine, A., Lightfoot, P. & Morrison, F. D., 11 Dec 2012, In: Chemistry of Materials. 24, 23, p. 4563-4571 9 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile -
The Polar Phase of NaNbO3: A Combined Study by Powder Diffraction, Solid-State NMR, and First-Principles Calculations
Johnston, K. E., Tang, C. C., Parker, J. E., Knight, K. S., Lightfoot, P. & Ashbrook, S. E., 30 Jun 2010, In: Journal of the American Chemical Society. 132, 25, p. 8732-8746 15 p.Research output: Contribution to journal › Article › peer-review
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An ionothermally prepared S=1/2 vanadium oxyfluoride kagome lattice
Himeur, F. H., Aldous, D. W., Goff, R. J., Slawin, A. M. Z., Attfield, J. P., Morris, R. E. & Lightfoot, P., Oct 2011, In: Nature Chemistry. 3, 10, p. 801-806 6 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile
Datasets
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Structural Diversity of Lead Halide Chain Compounds, APbX3, Templated by Isomeric Molecular Cations (dataset)
Guo, Y. (Creator) & Lightfoot, P. (Creator), University of St Andrews, 2020
DOI: 10.17630/6fe63429-e37e-4193-a61b-7380e7a3a1e8
Dataset
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Structural Variations in (001)-Oriented Layered Lead Halide Perovskites, Templated by 1,2,4-Triazolium (dataset)
Guo, Y. (Creator), Yang, L. (Creator), McNulty, J. A. (Creator), Slawin, A. M. Z. (Creator) & Lightfoot, P. (Creator), University of St Andrews, 12 Nov 2020
DOI: 10.17630/8ec43b91-782a-4c56-9501-eb7a700e1e48
Dataset
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Halogen Molecule Intercalation in Layered Hybrid Perovskites (thesis data)
Yang, L. (Creator), Payne, J. L. (Supervisor) & Lightfoot, P. (Supervisor), University of St Andrews, 9 Nov 2029
DOI: 10.17630/d08250cf-f3f2-4a3a-98cb-08157855ec24
Dataset: Thesis dataset
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Three new lead iodide chain compounds, APbI3, templated by molecular cations (dataset)
Lightfoot, P. (Creator), Guo, Y. (Creator) & Yang, L. (Creator), University of St Andrews, Nov 2019
DOI: 10.17630/bb979bce-5a77-45cf-b0c4-dfa7bd5c4588
Dataset
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Data underpinning article "Unprecedented phase transition sequence in the perovskite Li0.2Na0.8NbO3 "
Dixon, C. A. L. (Creator), McNulty, J. A. (Creator), Huband, S. (Creator), Thomas, P. A. (Creator) & Lightfoot, P. (Creator), University of St Andrews, 27 Mar 2017
DOI: 10.17630/c97a6cc7-05e8-4f3a-b881-0ee334dee69d
Dataset
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Projects
- 9 Finished
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Measurement Suite for the Accelerated: Measurement Suite for the Accelerated Design of Advanced, Quantum and Functional Materials
Lee, S. (PI), Brown, C. T. A. (CoI), Irvine, J. (CoI), King, P. (CoI), Lightfoot, P. (CoI), Rost, A. (CoI) & Wahl, P. (CoI)
1/11/20 → 31/10/22
Project: Standard
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Design & synthesis of new fluoride: Design and synthesis of new fluoride cathode materials for solid-state batteries
Lightfoot, P. (PI)
1/02/15 → 31/01/17
Project: Fellowship
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Quantum Spin Liquids: New Chemical Paradigms in the Search for Quantum Spin Liquids
Lightfoot, P. (PI) & Morris, R. (CoI)
1/06/14 → 31/08/17
Project: Standard
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A crystal-chemical Approach: A Crystal-chemical approach to New Frustrated Magnets
Lightfoot, P. (PI)
1/09/12 → 31/08/14
Project: Standard
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New Fluoride-based Magnetoe EP/F055722/1: New Fluoride-based Magnetoelctrics
Lightfoot, P. (PI), Baker, R. (CoI) & Morrison, F. (CoI)
1/06/08 → 30/09/11
Project: Standard
Activities
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International Symposium on Materials Chemistry, Bombay
Lightfoot, P. (Invited speaker)
2012Activity: Talk or presentation types › Invited talk
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17th European Symposium on Fluorine Chemistry, Paris
Lightfoot, P. (Invited speaker)
21 Jul 2013 → 25 Jul 2013Activity: Talk or presentation types › Invited talk
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Diamond Light Source (External organisation)
Lightfoot, P. (Participant)
2010 → …Activity: Membership types › Membership of peer review panel or committee
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International Symposium on Applications of Ferroelectrics, Edinburgh
Lightfoot, P. (Invited speaker)
2010Activity: Talk or presentation types › Invited talk
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Electronic Materials and Applications, Orlando, Florida
Lightfoot, P. (Invited speaker)
22 Jan 2014 → 24 Jan 2014Activity: Talk or presentation types › Invited talk