Personal profile
Profile Keywords
Molecular and supramolecular self-assembly; surface science; liquid/solid interfaces, nanoscience, electrochemistry
Academic/Professional Qualification
Chemistry (Dipl.), University of Heidelberg, Germany (1984)
PhD (Dr rer nat), University of Heidelberg, Germany (1988)
Postdoctoral Research Fellow, IBM Research, Almaden CA, USA (1988/89)
Research group leader, University of Heidelberg, Germany (1990-2000)
Habilitation in physical chemistry, University of Heidelberg, Germany (1994)
Reader in physical chemistry, University of St Andrews (2000)
Professor (2011-)
Teaching activity
MB contributes to teaching at both sub-Honours and Honours level. CH3721 Physical Chemistry Lab (module convenor), CH4715 (Lectures on Functional Materials), CH4716 (Lectures on electrochemistry, module convenor), CH4458 (Distance Learning, Electrochemistry), CH5717 (Lectures on Nanomaterials). Academic monitor for external placements (CH4441). Tutor for CH2701. Advisor of Studies for Chemistry at Honours level.
Research overview
In search for strategies which provide routine access to the bottom end of the nanoscale our research focuses on fundamental studies of processes at the solid-liquid interface as well as the generation of nanostructures using both lithographic top-down and self-assembly bottom-up procedures.
Employing organic molecules as most versatile and atomically precise building blocks, a main theme is the understanding of design principles of single and multi-component systems on solid substrates ranging from monolayers of densely packed molecules to hybrid structures involving two-dimensional supramolecular networks. Through an understanding of the complex interplay between structural features, intermolecular and molecule-substrate interactions we pursue new directions in molecular assembly and functionalisation of two-dimensional molecular assemblies, including studies of chemical reactivity at the single molecule level.
Another focus of our research, which capitalizes on the tailoring of interfacial properties by molecular assemblies, is their application as templates for the replicative generation of nanoscaled objects. Chemical functionalization and control of interfacial charge transfer by molecular systems are harnessed for the electrodeposition of metals and metal oxides as clusters or extended ultrathin nanostructured patterns of interest for catalysis, electronics, and optics. Indispensible tools for our work are scanning probe microscopies and electron spectroscopies.
Expertise related to UN Sustainable Development Goals
In 2015, UN member states agreed to 17 global Sustainable Development Goals (SDGs) to end poverty, protect the planet and ensure prosperity for all. This person’s work contributes towards the following SDG(s):
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SDG 7 Affordable and Clean Energy
Fingerprint
- 1 Similar Profiles
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Coordination controlled electrodeposition and patterning of layers of palladium/copper nanoparticles on top of a self-assembled monolayer
She, Z., Yao, Z., Ménard, H., Tobish, S., Lahaye, D., Champness, N. R. & Buck, M., 15 Jul 2019, (E-pub ahead of print) In: Nanoscale. Advance ArticleResearch output: Contribution to journal › Article › peer-review
Open AccessFile -
Self-assembly of 1,3,5-benzenetribenzoic acid on Ag and Cu at the liquid/solid interface
Aitchison, H., Lu, H., Ortiz de la Morena, R., Cebula, I., Zharnikov, M. & Buck, M., 28 Jan 2018, In: Physical Chemistry Chemical Physics. 20, 4, p. 2731-2740Research output: Contribution to journal › Article › peer-review
Open AccessFile -
Underpotential deposition of Cu on Au(111) from neutral chloride containing electrolyte
Aitchison, H., Meyerbroker, N., Lee, T.-L., Zegenhagen, J., Potter, T., Früchtl, H. A., Cebula, I. & Buck, M., 21 Sept 2017, In: Physical Chemistry Chemical Physics. 19, 35, p. 24146-24153 8 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile -
Sequential nested assembly at the liquid/solid interface
Karamzadeh, B., Eaton, T., Muñoz Torres, D., Cebula, I., Mayor, M. & Buck, M., 1 Oct 2017, In: Faraday Discussions. 204, p. 173-190 18 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile -
Self-assembled monolayers of oligophenylenecarboxylic acids on silver formed at the liquid-solid interface
Aitchison, H., Lu, H., Hogan, S. W. L., Fruchtl, H. A., Cebula, I., Zharnikov, M. & Buck, M., 20 Sept 2016, In: Langmuir. 32, 37, p. 9397-9409 13 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile
Datasets
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Self-Assembly of Molecules at the Solid-Liquid Interface on Silver and Gold Surfaces: The Challenge of the Complex Interplay of Interactions (thesis data)
Munro, K. J. M. (Creator) & Buck, M. (Supervisor), University of St Andrews, 5 Nov 2027
DOI: 10.17630/b33ea795-2708-41bf-aab9-0ed07852cf30
Dataset: Thesis dataset
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Coordination Controlled Electrodeposition and Patterning of Layers of Palladium/Copper Nanoparticles on Top of a Self-Assembled Monolayer (dataset)
She, Z. (Creator), Yao, Z. (Creator), Ménard, H. (Creator), Tobish, S. (Creator), Lahaye, D. (Creator), Champness, N. R. (Creator) & Buck, M. (Creator), University of St Andrews, 2019
DOI: 10.17630/9d2592bc-bdac-49b2-bc7b-f456957304ab
Dataset
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Self-Assembly of Di(pyrazol-1-yl)Pyridine-Benzoic Acid on Underpotentially Deposited Ag from Solution (dataset)
Aitchison, H. (Creator), Ortiz De La Morena, R. M. (Creator), Peifer, R. (Creator), Omar, S. (Creator), Lu, H. (Creator), Francis, S. M. (Creator), Zharnikov, M. (Creator), Grohmann, A. (Creator) & Buck, M. (Creator), University of St Andrews, 24 Jul 2018
DOI: 10.17630/b77a81c5-2ab6-47ca-af7b-afaefb75266b
Dataset
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Electron-Induced Modification of Self-Assembled Monolayers of Aromatic Carboxylic Acids (dataset)
Asyuda, A. (Creator), Ortiz De La Morena, R. M. (Creator), Sauter, E. (Creator), Turner, K. (Creator), McDonald, K. (Creator), Buck, M. (Creator) & Zharnikov, M. (Creator), University of St Andrews, 2020
DOI: 10.17630/599c89c3-b033-499d-b4bb-771805c05b28
Dataset
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Coordination-Controlled Electrodeposition of Palladium/Copper Thin Films onto a Pyridine-Terminated Self-Assembled Monolayer (dataset)
Yao, Z. (Creator), Naden, A. B. (Creator), Baker, R. (Creator) & Buck, M. (Creator), University of St Andrews, 24 Nov 2022
DOI: 10.17630/b047a584-c933-481e-ab71-be8c6d3e9097
Dataset
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Projects
- 10 Finished
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Metal Electrodeposition: Metal Electrodeposition Mediated by Carbon Nanomembranes
Buck, M. (PI)
1/03/23 → 28/02/25
Project: Standard
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Supramolecular: Supramolecular Self-Assemblies as Nanotemplates for Electrodeposition
Buck, M. (PI)
1/11/13 → 31/10/15
Project: Standard
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EPSRC Strategic partner projects applica: An electrochemical approach to loss management in plasmonic structures
Buck, M. (PI)
1/08/11 → 30/06/12
Project: Standard
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Royal Society Conference Grant 2008/R3: PRIME pacific rim meeting on electrochemical and solid state science
Buck, M. (PI)
12/10/08 → 17/10/08
Project: Standard
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Can gold assist in the global arsenic: Can gold assist in the global arsenic problem? Insights from speciation and development of an on-site system
Buck, M. (PI)
1/08/08 → 30/06/12
Project: Standard