Personal profile
Research overview
We study various research themes in synthetic molecular inorganic and organometallic chemistry with elements from across the periodic table, especially with compounds and complexes of main group elements. Many main group elements are highly Earth abundant, cheap, non-toxic and even biocompatible, and thus are ideally suited for sustainable applications. We discover and investigate fundamentally new compound classes including those with elements in rare oxidation states, unusually bonded fragments and reactive metal hydride species. These generally show novel structures, have unseen properties and as a consequence often show a unique reactivity. We employ these compounds in synthesis, catalysis and towards other applications.
Biography
Andreas studied chemistry at the University of Göttingen (Germany) and completed his chemistry diploma (Dipl.-Chem.) in 2000 and his Dr. rer. nat. (PhD) in 2003 under the supervision of Prof. Herbert W. Roesky. He conducted postdoctoral research with Prof. Cameron Jones at Cardiff University (2004-2006), including a stay with Prof. Peter C. Junk at Monash University (Melbourne, Australia) in 2005. Between 2007 and 2016, he held ARC-funded research fellowships (ARF, Future Fellowship) at the School of Chemistry, Monash University. Since 2016, he is a Reader at the School of Chemistry at the University of St Andrews. In 2010 he was awarded the Alan Sargeson Lectureship and in 2014 the Organometallic Chemistry Award by the Royal Australian Chemical Institute. Andreas' group works in numerous areas of molecular inorganic and organometallic chemistry with a focus on the main group elements. Of particular interest are novel low oxidation state compounds, metal hydride complexes, main group organometallics and their stoichiometric and catalytic reactivity.
Teaching activity
Andreas teaches at both sub-honours and honours level and lectures in CH2501 (Inorganic Chemistry 2), CH3512 (Organometallic Chemistry, Module convenor) and CH4515 (Advanced Main Group Chemistry). Andreas also contributes to the laboratory components of CH1401 (Introductory Inorganic and Physical Chemistry) and CH3521 (Inorganic Chemistry Laboratory), tutorials for various modules, as academic monitor for external placements and various module assessments.
Profile Keywords
Main group chemistry; low oxidation state compounds; metal hydride complexes; organometallic synthesis and catalysis; ligand design
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Collaborations and top research areas from the last five years
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Facile, reversible hydrogen activation by low-coordinate magnesium oxide complexes
Thompson, S., Burnett, S., Ferns, R., van Mourik, T., McKay, A. P., Slawin, A. M. Z., Cordes, D. B. & Stasch, A., 28 Jan 2025, (E-pub ahead of print) In: Journal of the American Chemical Society. Ahead of Print, 11 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile -
Umpolung of an aliphatic ketone to a magnesium ketone-1,2-diide complex with vicinal dianionic charge
Burnett, S., Bourne, C., Slawin, A. M. Z., van Mourik, T. & Stasch, A., 16 Aug 2022, In: Angewandte Chemie International Edition. 61, 34, 10 p., e202204472.Research output: Contribution to journal › Article › peer-review
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Hydrocarbon-soluble, hexaanionic fulleride complexes of magnesium
Lawrence, S., Ohlin, C. A., Cordes, D. B., Slawin, A. M. Z. & Stasch, A., 14 Dec 2019, In: Chemical Science. 10, 46, p. 10755-10764 10 p.Research output: Contribution to journal › Article › peer-review
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Anion stabilised hypercloso-hexaalane Al6H6
Bonyhady, S. J., Collis, D., Holzmann, N., Edwards, A. J., Piltz, R. O., Frenking, G., Stasch, A. & Jones, C., 6 Aug 2018, In: Nature Communications. 9, p. 1-6 6 p., 3079.Research output: Contribution to journal › Article › peer-review
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Synthesis, characterization, and computational analysis of the dialanate dianion, [H3Al-AlH3]2−: a valence isoelectronic analogue of ethane
Bonyhady, S. J., Holzmann, N., Frenking, G., Stasch, A. & Jones, C., 10 Jul 2017, In: Angewandte Chemie International Edition. 56, 29, p. 8527-8531 5 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile
Datasets
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Data underpinning Nikita Demidov's thesis
Demidov, N. (Creator) & Stasch, A. (Supervisor), University of St Andrews, 21 Apr 2028
DOI: 10.17630/c7942ba3-96a8-42d6-be33-9a5195192d6e
Dataset: Thesis dataset
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Data underpinning Stuart Burnett's thesis
Burnett, S. (Creator) & Stasch, A. (Supervisor), University of St Andrews, 28 Jan 2024
DOI: 10.17630/57d4d24c-729d-4c0f-8bde-066d16c62cfe, https://doi.org/10.17630/sta/274
Dataset: Thesis dataset
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Ligand Variations in Low Oxidation State Group 13 and Group 14 Compounds: Synthesis, Characterisation, and Novel Reactivity (Thesis data)
Dong, H. (Creator) & Stasch, A. (Supervisor), University of St Andrews, 20 Oct 2028
DOI: 10.17630/5b74ef65-65d0-45de-9481-1c2a64038910
Dataset: Thesis dataset
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Data underpinning Sam Lawrence's thesis
Lawrence, S. (Creator), Slawin, A. M. Z. (Contributor), Stasch, A. (Supervisor), Cordes, D. B. (Contributor) & Ohlin, C. A. (Contributor), University of St Andrews, 21 Mar 2026
DOI: 10.17630/961ee837-4f1a-46d4-ab1b-1a053f0006dc
Dataset: Thesis dataset
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An extremely bulky tris(pyrazolyl)methanide: a tridentate ligand for the synthesis of heteroleptic magnesium(II) and ytterbium(II) alkyl, hydride, and iodide complexes (dataset)
Lalrempuia, R. (Creator), Stasch, A. (Creator) & Jones, C. (Creator), Cambridge Crystallographic Data Centre, 2014
https://dx.doi.org/10.5517/cc13db83 and 7 more links, https://dx.doi.org/10.5517/cc13db94, https://dx.doi.org/10.5517/cc13dbb5, https://dx.doi.org/10.5517/cc13dbc6, https://dx.doi.org/10.5517/cc13dbd7, https://dx.doi.org/10.5517/cc13dbf8, https://dx.doi.org/10.5517/cc13dbg9, https://dx.doi.org/10.5517/cc13dbhb (show fewer)
Dataset